Copolymerization of Ethylene and Propylene with Functionalized Vinyl Monomers by Palladium(II) Catalysts

Kurzanzeige
dc.contributor.authorJohnson, Lynda K.deu
dc.contributor.authorMecking, Stefan
dc.contributor.authorBrookhart, Mauricedeu
dc.date.accessioned2011-03-24T18:12:36Zdeu
dc.date.issued1996deu
dc.description.abstractZiegler-Natta and related catalysts based on early transition metal d0 complexes are extensively used for the coordination polymerization of nonpolar olefins such as ethylene and propylene. However, due to their highly oxophilic nature, these catalysts are incompatible with functionalized vinyl monomers. Late transition metal catalysts are less oxophilic, but they most often dimerize or oligomerize olefins rather than form high molar mass polymers. Thus, ethylene-acrylate or ethyleneviny acetate copolymers are still exclusively produced by radical routes, which often require high pressure.eng
dc.description.versionpublished
dc.embargo.terms2100-01-01deu
dc.format.mimetypeapplication/pdfdeu
dc.identifier.citationFirst publ. in: Journal of the American Chemical Society ; 118 (1996), 1. S. 267-268deu
dc.identifier.doi10.1021/ja953247i
dc.identifier.ppn284906840deu
dc.identifier.urihttp://kops.uni-konstanz.de/handle/123456789/9540
dc.language.isoengdeu
dc.legacy.dateIssued2008deu
dc.rightsAttribution-NonCommercial-NoDerivs 2.0 Generic
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/2.0/
dc.subject.ddc540deu
dc.titleCopolymerization of Ethylene and Propylene with Functionalized Vinyl Monomers by Palladium(II) Catalystseng
dc.typeJOURNAL_ARTICLEdeu
dspace.entity.typePublication
kops.citation.bibtex
@article{Johnson1996Copol-9540,
  year={1996},
  doi={10.1021/ja953247i},
  title={Copolymerization of Ethylene and Propylene with Functionalized Vinyl Monomers by Palladium(II) Catalysts},
  number={1},
  volume={118},
  issn={0002-7863},
  journal={Journal of the American Chemical Society},
  pages={267--268},
  author={Johnson, Lynda K. and Mecking, Stefan and Brookhart, Maurice}
}
kops.citation.iso690JOHNSON, Lynda K., Stefan MECKING, Maurice BROOKHART, 1996. Copolymerization of Ethylene and Propylene with Functionalized Vinyl Monomers by Palladium(II) Catalysts. In: Journal of the American Chemical Society. 1996, 118(1), pp. 267-268. ISSN 0002-7863. eISSN 1520-5126. Available under: doi: 10.1021/ja953247ideu
kops.citation.iso690JOHNSON, Lynda K., Stefan MECKING, Maurice BROOKHART, 1996. Copolymerization of Ethylene and Propylene with Functionalized Vinyl Monomers by Palladium(II) Catalysts. In: Journal of the American Chemical Society. 1996, 118(1), pp. 267-268. ISSN 0002-7863. eISSN 1520-5126. Available under: doi: 10.1021/ja953247ieng
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temp.date.embargoEnd2100-01-01deu

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