Publikation: Theory of thermodynamic stresses in colloidal dispersions at the glass transition
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2008
Autor:innen
Hajnal, David
Henrich, Oliver
Crassous, Jérôme J.
Siebenbürger, Miriam
Drechsler, Markus
Ballauff, Matthias
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We discuss the nonlinear rheology of dense colloidal dispersions at the glass transition. A first principles approach starting with interacting Brownian particles in given arbitrary homogeneous (incompressible) flow neglecting hydrodynamic interactions is sketched. It e.g. explains steady state flow curves for finite shear rates measured in dense suspensions of thermosensitive core-shell particles consisting of a polystyrene core and a crosslinked poly(N-isopropylacrylamide)(PNIPAM) shell. The exponents of simple and generalized Herschel Bulkley laws are computed for hard spheres.
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HAJNAL, David, Oliver HENRICH, Jérôme J. CRASSOUS, Miriam SIEBENBÜRGER, Markus DRECHSLER, Matthias BALLAUFF, Matthias FUCHS, 2008. Theory of thermodynamic stresses in colloidal dispersions at the glass transitionBibTex
@unpublished{Hajnal2008Theor-5252, year={2008}, doi={10.1063/1.2964805}, title={Theory of thermodynamic stresses in colloidal dispersions at the glass transition}, author={Hajnal, David and Henrich, Oliver and Crassous, Jérôme J. and Siebenbürger, Miriam and Drechsler, Markus and Ballauff, Matthias and Fuchs, Matthias} }
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