Magnetic field effect on picosecond electron transfer

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dc.contributor.authorGilch, Peterdeu
dc.contributor.authorPöllinger-Dammer, Floriandeu
dc.contributor.authorMusewald, Christiandeu
dc.contributor.authorMichel-Beyerle, Maria Elisabethdeu
dc.contributor.authorSteiner, Ulrich
dc.date.accessioned2011-03-24T18:16:09Zdeu
dc.date.available2011-03-24T18:16:09Zdeu
dc.date.issued1998deu
dc.description.abstractThe recombination dynamics of a transition metal redox system monitored by femtosecond pump-probe spectroscopy are shown to be sensitive to high magnetic fields at times shorter than 10 picoseconds. The effect, based on coherent population beats of different spin states, is quantitatively accounted for and allows direct access to spin relaxation rates far beyond the time resolution of the fastest electron paramagnetic resonance technique. The presence of this ultrafast magnetic field effect helps in understanding complex reaction schemes in transition metal chemistry, which occur in a wide range of fields, such as bioinorganic chemistry and catalysis.eng
dc.description.versionpublished
dc.format.mimetypeapplication/pdfdeu
dc.identifier.citationFirst publ. in: Science 281 (1998), 5379, pp. 982-984deu
dc.identifier.doi10.1126/science.281.5379.982
dc.identifier.ppn276956109deu
dc.identifier.urihttp://kops.uni-konstanz.de/handle/123456789/10037
dc.language.isoengdeu
dc.legacy.dateIssued2008deu
dc.rightsAttribution-NonCommercial-NoDerivs 2.0 Generic
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/2.0/
dc.subject.ddc540deu
dc.titleMagnetic field effect on picosecond electron transfereng
dc.typeJOURNAL_ARTICLEdeu
dspace.entity.typePublication
kops.citation.bibtex
@article{Gilch1998Magne-10037,
  year={1998},
  doi={10.1126/science.281.5379.982},
  title={Magnetic field effect on picosecond electron transfer},
  number={5379},
  volume={281},
  journal={Science},
  pages={982--984},
  author={Gilch, Peter and Pöllinger-Dammer, Florian and Musewald, Christian and Michel-Beyerle, Maria Elisabeth and Steiner, Ulrich}
}
kops.citation.iso690GILCH, Peter, Florian PÖLLINGER-DAMMER, Christian MUSEWALD, Maria Elisabeth MICHEL-BEYERLE, Ulrich STEINER, 1998. Magnetic field effect on picosecond electron transfer. In: Science. 1998, 281(5379), pp. 982-984. Available under: doi: 10.1126/science.281.5379.982deu
kops.citation.iso690GILCH, Peter, Florian PÖLLINGER-DAMMER, Christian MUSEWALD, Maria Elisabeth MICHEL-BEYERLE, Ulrich STEINER, 1998. Magnetic field effect on picosecond electron transfer. In: Science. 1998, 281(5379), pp. 982-984. Available under: doi: 10.1126/science.281.5379.982eng
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kops.sourcefield.plainScience. 1998, 281(5379), pp. 982-984. Available under: doi: 10.1126/science.281.5379.982eng
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