Thermoplastic Polyurethane Elastomers with Aliphatic Hard Segments Based on Plant-Oil-Derived Long-Chain Diisocyanates
| dc.contributor.author | Schemmer, Brigitta | |
| dc.contributor.author | Kronenbitter, Cathrin | |
| dc.contributor.author | Mecking, Stefan | |
| dc.date.accessioned | 2018-03-14T09:01:02Z | |
| dc.date.available | 2018-03-14T09:01:02Z | |
| dc.date.issued | 2018-04 | |
| dc.description.abstract | Novel plant-oil-derived long-chain (C19 and C23) α,ω-diisocyanates, optionally in combination with the corresponding long-chain diols, provide entirely aliphatic hard segments in segmented thermoplastic polyurethane elastomers (TPUs), with carbohydrate-based poly(trimethylene glycol) soft segments. Compared to materials based on a mid-chain monomer analog, phase separation is higher due to an increased flexibility of the aliphatic segments. Although melting points are slightly lower than for HDPE, the long-chain TPU's solid-state structure is still dominated by hydrogen-bonding. | eng |
| dc.description.version | published | eng |
| dc.identifier.doi | 10.1002/mame.201700416 | eng |
| dc.identifier.ppn | 511476116 | |
| dc.identifier.uri | https://kops.uni-konstanz.de/handle/123456789/41769 | |
| dc.language.iso | eng | eng |
| dc.rights | terms-of-use | |
| dc.rights.uri | https://rightsstatements.org/page/InC/1.0/ | |
| dc.subject.ddc | 540 | eng |
| dc.title | Thermoplastic Polyurethane Elastomers with Aliphatic Hard Segments Based on Plant-Oil-Derived Long-Chain Diisocyanates | eng |
| dc.type | JOURNAL_ARTICLE | eng |
| dspace.entity.type | Publication | |
| kops.citation.bibtex | @article{Schemmer2018-04Therm-41769,
year={2018},
doi={10.1002/mame.201700416},
title={Thermoplastic Polyurethane Elastomers with Aliphatic Hard Segments Based on Plant-Oil-Derived Long-Chain Diisocyanates},
number={4},
volume={303},
issn={0003-3146},
journal={Macromolecular Materials and Engineering},
author={Schemmer, Brigitta and Kronenbitter, Cathrin and Mecking, Stefan},
note={Article Number: 1700416}
} | |
| kops.citation.iso690 | SCHEMMER, Brigitta, Cathrin KRONENBITTER, Stefan MECKING, 2018. Thermoplastic Polyurethane Elastomers with Aliphatic Hard Segments Based on Plant-Oil-Derived Long-Chain Diisocyanates. In: Macromolecular Materials and Engineering. 2018, 303(4), 1700416. ISSN 0003-3146. eISSN 1439-2054. Available under: doi: 10.1002/mame.201700416 | deu |
| kops.citation.iso690 | SCHEMMER, Brigitta, Cathrin KRONENBITTER, Stefan MECKING, 2018. Thermoplastic Polyurethane Elastomers with Aliphatic Hard Segments Based on Plant-Oil-Derived Long-Chain Diisocyanates. In: Macromolecular Materials and Engineering. 2018, 303(4), 1700416. ISSN 0003-3146. eISSN 1439-2054. Available under: doi: 10.1002/mame.201700416 | eng |
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<dcterms:abstract xml:lang="eng">Novel plant-oil-derived long-chain (C<sub>19</sub> and C<sub>23</sub>) α,ω-diisocyanates, optionally in combination with the corresponding long-chain diols, provide entirely aliphatic hard segments in segmented thermoplastic polyurethane elastomers (TPUs), with carbohydrate-based poly(trimethylene glycol) soft segments. Compared to materials based on a mid-chain monomer analog, phase separation is higher due to an increased flexibility of the aliphatic segments. Although melting points are slightly lower than for HDPE, the long-chain TPU's solid-state structure is still dominated by hydrogen-bonding.</dcterms:abstract>
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| kops.sourcefield.plain | Macromolecular Materials and Engineering. 2018, 303(4), 1700416. ISSN 0003-3146. eISSN 1439-2054. Available under: doi: 10.1002/mame.201700416 | eng |
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| source.periodicalTitle | Macromolecular Materials and Engineering | eng |
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