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Conjugated Polymer Composite Nanoparticles by Rapid Mixing

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2014

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https://doi.org/10.1002/marc.201400384
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Macromolecular Rapid Communications. 2014, 35(23), pp. 2038-2042. ISSN 0173-2803. eISSN 1521-3927. Available under: doi: 10.1002/marc.201400384

Zusammenfassung

Composite nanoparticles from poly[(9,9-di-n-octylfluoren-2,7-diyl)-alt-(benzo[2,1,3]thiadiazol-4,8-diyl)] (F8BT) and poly(9,9-di-n-hexylfluoren-2,7-diyl) (PF) with embedded inorganic nanoparticles (TiO2, CdSe, and CdSe/CdS) are prepared through kinetic trapping by rapid turbulent mixing in a multi-inlet vortex mixer without the need for polymer functionalization. High contents of inorganic materials up to 50–60 wt% are realized for all composites. The influence of flow ratios, sodium dodecyl sulfate (SDS) concentration, and absolute flow rates on the particle size and morphology is studied. High water-to-THF ratios and high total flow rates around 2 m s−1 yield particle sizes below 50 nm. By adjusting these parameters, controlled particle sizes between 30 to several hundred nanometers are obtained. Composite particles from CdSe/CdS and F8BT or PF show a strong quenching of the polymer emission and near exclusive emission from the inorganic nanocrystal, which indicates an efficient energy transfer with fluorescence quantum yields of 23% for the F8BT/CdSe/CdS composites and 21% for the PF/CdSe/CdS composites. The dispersions are colloidally stable for several months.

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540 Chemie

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conjugated polymers, fluorescence, hybrid particles, multi-inlet vortex mixers, quantum dots

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ISO 690JUNG, Christoph, Tjaard DE ROO, Stefan MECKING, 2014. Conjugated Polymer Composite Nanoparticles by Rapid Mixing. In: Macromolecular Rapid Communications. 2014, 35(23), pp. 2038-2042. ISSN 0173-2803. eISSN 1521-3927. Available under: doi: 10.1002/marc.201400384
BibTex
@article{Jung2014Conju-29372,
  year={2014},
  doi={10.1002/marc.201400384},
  title={Conjugated Polymer Composite Nanoparticles by Rapid Mixing},
  number={23},
  volume={35},
  issn={0173-2803},
  journal={Macromolecular Rapid Communications},
  pages={2038--2042},
  author={Jung, Christoph and de Roo, Tjaard and Mecking, Stefan}
}
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