Cross-metathesis of vinylsilanes with olefins in the presence of Grubbs catalyst

Kurzanzeige
dc.contributor.authorPietraszuk, Cezarydeu
dc.contributor.authorFischer, Helmut
dc.contributor.authorKujawa, Malgorzatadeu
dc.contributor.authorMarciniec, Bogdandeu
dc.date.accessioned2011-03-24T18:13:17Zdeu
dc.date.available2011-03-24T18:13:17Zdeu
dc.date.issued2001deu
dc.description.abstractEffective cross-metathesis of H2C=C(H)SiR3, where SiR3=Si(OMe)3, Si(OEt)3, Si(OSiMe3)3, with selected olefins in the presence of (PCy3)2Cl2Ru(=CHPh) (I) is described. Treatment of p-substituted styrenes, 1-alkenes and selected allyl derivatives H2C=CHCH2R' (R'=SiMe3, Si(OEt)3, Ph, OPh) with an excess of H2C=C(H)SiR3 results in the formation of the respective cross-metathesis products with good yields and selectivities. The metallacarbene mechanism of the process is discussed.eng
dc.description.versionpublished
dc.format.mimetypeapplication/pdfdeu
dc.identifier.citationFirst publ. in: Tetrahedron Letters 42 (2001), pp. 1175 1178deu
dc.identifier.doi10.1016/S0040-4039(00)02201-2
dc.identifier.ppn26285516Xdeu
dc.identifier.urihttp://kops.uni-konstanz.de/handle/123456789/9627
dc.language.isoengdeu
dc.legacy.dateIssued2007deu
dc.rightsAttribution-NonCommercial-NoDerivs 2.0 Generic
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/2.0/
dc.subject.ddc540deu
dc.titleCross-metathesis of vinylsilanes with olefins in the presence of Grubbs catalysteng
dc.typeJOURNAL_ARTICLEdeu
dspace.entity.typePublication
kops.citation.bibtex
@article{Pietraszuk2001Cross-9627,
  year={2001},
  doi={10.1016/S0040-4039(00)02201-2},
  title={Cross-metathesis of vinylsilanes with olefins in the presence of Grubbs  catalyst},
  number={6},
  volume={42},
  issn={0040-4039},
  journal={Tetrahedron Letters},
  pages={1175--1178},
  author={Pietraszuk, Cezary and Fischer, Helmut and Kujawa, Malgorzata and Marciniec, Bogdan}
}
kops.citation.iso690PIETRASZUK, Cezary, Helmut FISCHER, Malgorzata KUJAWA, Bogdan MARCINIEC, 2001. Cross-metathesis of vinylsilanes with olefins in the presence of Grubbs catalyst. In: Tetrahedron Letters. 2001, 42(6), pp. 1175-1178. ISSN 0040-4039. Available under: doi: 10.1016/S0040-4039(00)02201-2deu
kops.citation.iso690PIETRASZUK, Cezary, Helmut FISCHER, Malgorzata KUJAWA, Bogdan MARCINIEC, 2001. Cross-metathesis of vinylsilanes with olefins in the presence of Grubbs catalyst. In: Tetrahedron Letters. 2001, 42(6), pp. 1175-1178. ISSN 0040-4039. Available under: doi: 10.1016/S0040-4039(00)02201-2eng
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kops.sourcefieldTetrahedron Letters. 2001, <b>42</b>(6), pp. 1175-1178. ISSN 0040-4039. Available under: doi: 10.1016/S0040-4039(00)02201-2deu
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kops.sourcefield.plainTetrahedron Letters. 2001, 42(6), pp. 1175-1178. ISSN 0040-4039. Available under: doi: 10.1016/S0040-4039(00)02201-2eng
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