Transfer of the carbyne ligand to the C≡C bond versus alkyne–carbyne–CO coupling in the reactions of [(η5-C5H5)(CO)2Mn≡CPh]+ with electron-rich alkynes

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dc.contributor.authorFischer, Helmut
dc.contributor.authorTroll, Carstendeu
dc.date.accessioned2013-06-26T09:31:19Zdeu
dc.date.available2013-06-26T09:31:19Zdeu
dc.date.issued1994
dc.description.abstractThe carbyne cation [(η5-C5H5)(CO)2Mn≡CPh]+1 reacts with bis(diorganylamino)acetylenes by transfer of the carbyne ligand to the C–C bond of the alkynes to give cyclopropenyl cations; in contrast, the reaction with diorganylaminopropyne affords novel η4-carbene complexes by regioselective coupling of the carbyne and one CO ligand with the alkyne.eng
dc.description.versionpublished
dc.identifier.citationJournal of the Chemical Society, Chemical Communications ; (1994), 4. - S. 457-458deu
dc.identifier.doi10.1039/C39940000457deu
dc.identifier.urihttp://kops.uni-konstanz.de/handle/123456789/23387
dc.language.isoengdeu
dc.legacy.dateIssued2013-06-26deu
dc.rightsterms-of-usedeu
dc.rights.urihttps://rightsstatements.org/page/InC/1.0/deu
dc.subject.ddc540deu
dc.titleTransfer of the carbyne ligand to the C≡C bond versus alkyne–carbyne–CO coupling in the reactions of [(η5-C5H5)(CO)2Mn≡CPh]+ with electron-rich alkyneseng
dc.typeJOURNAL_ARTICLEdeu
dspace.entity.typePublication
kops.citation.bibtex
@article{Fischer1994Trans-23387,
  year={1994},
  doi={10.1039/C39940000457},
  title={Transfer of the carbyne ligand to the C≡C bond versus alkyne–carbyne–CO coupling in the reactions of [(η5-C5H5)(CO)2Mn≡CPh]+ with electron-rich alkynes},
  number={4},
  issn={0022-4936},
  journal={Journal of the Chemical Society, Chemical Communications},
  pages={457--458},
  author={Fischer, Helmut and Troll, Carsten}
}
kops.citation.iso690FISCHER, Helmut, Carsten TROLL, 1994. Transfer of the carbyne ligand to the C≡C bond versus alkyne–carbyne–CO coupling in the reactions of [(η5-C5H5)(CO)2Mn≡CPh]+ with electron-rich alkynes. In: Journal of the Chemical Society, Chemical Communications. 1994(4), pp. 457-458. ISSN 0022-4936. Available under: doi: 10.1039/C39940000457deu
kops.citation.iso690FISCHER, Helmut, Carsten TROLL, 1994. Transfer of the carbyne ligand to the C≡C bond versus alkyne–carbyne–CO coupling in the reactions of [(η5-C5H5)(CO)2Mn≡CPh]+ with electron-rich alkynes. In: Journal of the Chemical Society, Chemical Communications. 1994(4), pp. 457-458. ISSN 0022-4936. Available under: doi: 10.1039/C39940000457eng
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kops.identifier.nbnurn:nbn:de:bsz:352-233877deu
kops.sourcefieldJournal of the Chemical Society, Chemical Communications. 1994(4), pp. 457-458. ISSN 0022-4936. Available under: doi: 10.1039/C39940000457deu
kops.sourcefield.plainJournal of the Chemical Society, Chemical Communications. 1994(4), pp. 457-458. ISSN 0022-4936. Available under: doi: 10.1039/C39940000457deu
kops.sourcefield.plainJournal of the Chemical Society, Chemical Communications. 1994(4), pp. 457-458. ISSN 0022-4936. Available under: doi: 10.1039/C39940000457eng
kops.submitter.emailkarin.hoch@uni-konstanz.dedeu
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source.identifier.issn0022-4936
source.periodicalTitleJournal of the Chemical Society, Chemical Communications

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