Alpha-Thioalkylation of Zinc Dienolates to 4-Substituted 1-tert-Butoxy-7a-methyl-hexahydroinden-5-ones

dc.contributor.authorGroth, Ulrich
dc.contributor.authorKöhler, Thomasdeu
dc.contributor.authorTaapken, Thomasdeu
dc.date.accessioned2011-03-24T18:14:03Zdeu
dc.date.available2011-03-24T18:14:03Zdeu
dc.date.issued1994deu
dc.description.abstractα-Alkylation of the α,β-unsaturated ketone 1 at C-4 has been achieved by thioalkylation of the corresponding zinc dienolate with α-chlorosulfides of type 2. The desulfurization of the β-(phenylthio) ketones 4 leads directly to the 4-substituted hexahydroinden-5-ones 5.deu
dc.description.versionpublished
dc.format.mimetypeapplication/pdfdeu
dc.identifier.citationFirst publ. in: Liebigs Annalen der Chemie 1994, 7, pp. 665-668deu
dc.identifier.ppn276767004deu
dc.identifier.urihttp://kops.uni-konstanz.de/handle/123456789/9739
dc.language.isoengdeu
dc.legacy.dateIssued2008deu
dc.rightsAttribution-NonCommercial-NoDerivs 2.0 Generic
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/2.0/
dc.subjectZinc dienolatesdeu
dc.subjectthioalkylation of / Indenes / Steroidsdeu
dc.subject.ddc540deu
dc.titleAlpha-Thioalkylation of Zinc Dienolates to 4-Substituted 1-tert-Butoxy-7a-methyl-hexahydroinden-5-oneseng
dc.typeJOURNAL_ARTICLEdeu
dspace.entity.typePublication
kops.citation.bibtex
@article{Groth1994Alpha-9739,
  year={1994},
  title={Alpha-Thioalkylation of Zinc Dienolates to 4-Substituted 1-tert-Butoxy-7a-methyl-hexahydroinden-5-ones},
  number={7},
  journal={Liebigs Annalen der Chemie},
  pages={665--668},
  author={Groth, Ulrich and Köhler, Thomas and Taapken, Thomas}
}
kops.citation.iso690GROTH, Ulrich, Thomas KÖHLER, Thomas TAAPKEN, 1994. Alpha-Thioalkylation of Zinc Dienolates to 4-Substituted 1-tert-Butoxy-7a-methyl-hexahydroinden-5-ones. In: Liebigs Annalen der Chemie. 1994(7), pp. 665-668deu
kops.citation.iso690GROTH, Ulrich, Thomas KÖHLER, Thomas TAAPKEN, 1994. Alpha-Thioalkylation of Zinc Dienolates to 4-Substituted 1-tert-Butoxy-7a-methyl-hexahydroinden-5-ones. In: Liebigs Annalen der Chemie. 1994(7), pp. 665-668eng
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