Adiabatic rotation of effective spin. 11. Spin-rotational relaxation

Kurzanzeige
dc.contributor.authorSteiner, Ulrich
dc.contributor.authorSerebrennikov, Yuri A.deu
dc.date.accessioned2011-03-24T18:14:58Zdeu
dc.date.available2011-03-24T18:14:58Zdeu
dc.date.issued1994deu
dc.description.abstractThe theory of electron spin-rotational (SR) relaxation in systems with an effective spin Seff=1/2 is formulated in terms of the adiabatic rotation of effective spin (ARES) approach. It is shown that SR relaxation results from the orientational random walk of the axes of the intramolecular electric field potential (ligand field) to which a spin-bearing atomic center is exposed. The validity of the stochastic treatment presented here is not limited by the Redfield conditions. The general expression obtained for the time constant of electron spin relaxation in liquid phase reproduces the well-known result of Hubbard-Atkins-Kivelson theory if it is specialized to the case of systems with weak spin-orbit coupling.eng
dc.description.versionpublished
dc.format.mimetypeapplication/pdfdeu
dc.identifier.citationFirst publ. in: Journal of Chemical Physics 100 (1994), 10, pp. 7508-7514deu
dc.identifier.doi10.1063/1.466843
dc.identifier.ppn287976637deu
dc.identifier.urihttp://kops.uni-konstanz.de/handle/123456789/9870
dc.language.isoengdeu
dc.legacy.dateIssued2008deu
dc.rightsAttribution-NonCommercial-NoDerivs 2.0 Generic
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/2.0/
dc.subject.ddc540deu
dc.titleAdiabatic rotation of effective spin. 11. Spin-rotational relaxationeng
dc.typeJOURNAL_ARTICLEdeu
dspace.entity.typePublication
kops.citation.bibtex
@article{Steiner1994Adiab-9870,
  year={1994},
  doi={10.1063/1.466843},
  title={Adiabatic rotation of effective spin. 11. Spin-rotational relaxation},
  number={10},
  volume={100},
  issn={0021-9606},
  journal={Journal of Chemical Physics},
  pages={7508--7514},
  author={Steiner, Ulrich and Serebrennikov, Yuri A.}
}
kops.citation.iso690STEINER, Ulrich, Yuri A. SEREBRENNIKOV, 1994. Adiabatic rotation of effective spin. 11. Spin-rotational relaxation. In: Journal of Chemical Physics. 1994, 100(10), pp. 7508-7514. ISSN 0021-9606. Available under: doi: 10.1063/1.466843deu
kops.citation.iso690STEINER, Ulrich, Yuri A. SEREBRENNIKOV, 1994. Adiabatic rotation of effective spin. 11. Spin-rotational relaxation. In: Journal of Chemical Physics. 1994, 100(10), pp. 7508-7514. ISSN 0021-9606. Available under: doi: 10.1063/1.466843eng
kops.citation.rdf
<rdf:RDF
    xmlns:dcterms="http://purl.org/dc/terms/"
    xmlns:dc="http://purl.org/dc/elements/1.1/"
    xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#"
    xmlns:bibo="http://purl.org/ontology/bibo/"
    xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#"
    xmlns:foaf="http://xmlns.com/foaf/0.1/"
    xmlns:void="http://rdfs.org/ns/void#"
    xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > 
  <rdf:Description rdf:about="https://kops.uni-konstanz.de/server/rdf/resource/123456789/9870">
    <dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/>
    <dcterms:hasPart rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/9870/1/Steiner_1994_Adiabatic.pdf"/>
    <dc:format>application/pdf</dc:format>
    <dc:creator>Steiner, Ulrich</dc:creator>
    <dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/>
    <void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/>
    <dcterms:issued>1994</dcterms:issued>
    <dcterms:rights rdf:resource="http://creativecommons.org/licenses/by-nc-nd/2.0/"/>
    <dc:creator>Serebrennikov, Yuri A.</dc:creator>
    <dc:contributor>Serebrennikov, Yuri A.</dc:contributor>
    <dc:contributor>Steiner, Ulrich</dc:contributor>
    <dc:rights>Attribution-NonCommercial-NoDerivs 2.0 Generic</dc:rights>
    <foaf:homepage rdf:resource="http://localhost:8080/"/>
    <dspace:hasBitstream rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/9870/1/Steiner_1994_Adiabatic.pdf"/>
    <dcterms:title>Adiabatic rotation of effective spin. 11. Spin-rotational relaxation</dcterms:title>
    <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T18:14:58Z</dcterms:available>
    <dc:language>eng</dc:language>
    <dcterms:abstract xml:lang="eng">The theory of electron spin-rotational (SR) relaxation in systems with an effective spin Seff=1/2 is formulated in terms of the adiabatic rotation of effective spin (ARES) approach. It is shown that SR relaxation results from the orientational random walk of the axes of the intramolecular electric field potential (ligand field) to which a spin-bearing atomic center is exposed. The validity of the stochastic treatment presented here is not limited by the Redfield conditions. The general expression obtained for the time constant of electron spin relaxation in liquid phase reproduces the well-known result of Hubbard-Atkins-Kivelson theory if it is specialized to the case of systems with weak spin-orbit coupling.</dcterms:abstract>
    <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/9870"/>
    <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T18:14:58Z</dc:date>
    <dcterms:bibliographicCitation>First publ. in: Journal of Chemical Physics 100 (1994), 10, pp. 7508-7514</dcterms:bibliographicCitation>
  </rdf:Description>
</rdf:RDF>
kops.description.openAccessopenaccessgreen
kops.flag.knbibliographyfalse
kops.identifier.nbnurn:nbn:de:bsz:352-opus-68153deu
kops.opus.id6815deu
kops.sourcefieldJournal of Chemical Physics. 1994, <b>100</b>(10), pp. 7508-7514. ISSN 0021-9606. Available under: doi: 10.1063/1.466843deu
kops.sourcefield.plainJournal of Chemical Physics. 1994, 100(10), pp. 7508-7514. ISSN 0021-9606. Available under: doi: 10.1063/1.466843deu
kops.sourcefield.plainJournal of Chemical Physics. 1994, 100(10), pp. 7508-7514. ISSN 0021-9606. Available under: doi: 10.1063/1.466843eng
relation.isAuthorOfPublicationa58563b1-7fc1-4229-b33e-7f14f5f38686
relation.isAuthorOfPublication.latestForDiscoverya58563b1-7fc1-4229-b33e-7f14f5f38686
source.bibliographicInfo.fromPage7508
source.bibliographicInfo.issue10
source.bibliographicInfo.toPage7514
source.bibliographicInfo.volume100
source.identifier.issn0021-9606
source.periodicalTitleJournal of Chemical Physics

Dateien

Originalbündel

Gerade angezeigt 1 - 1 von 1
Vorschaubild nicht verfügbar
Name:
Steiner_1994_Adiabatic.pdf
Größe:
270.01 KB
Format:
Adobe Portable Document Format
Steiner_1994_Adiabatic.pdf
Steiner_1994_Adiabatic.pdfGröße: 270.01 KBDownloads: 374

Sammlungen

Chemie: Publikationen