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Application of integral encounter theory to account for the spin effects in radical reactions (I) : g and spin relaxation effects on recombination kinetics of free radicals

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2000

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Gorelik, Elena V.
Lukzen, Nikita N.
Sagdeev, Renad Z.

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Chemical Physics. 2000, 262(2-3), pp. 303-323. ISSN 0301-0104. Available under: doi: 10.1016/S0301-0104(00)00312-8

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Integral encounter theory is applied to investigate spin effects in radical recombination. Effects of electron spin relaxation and of S/T0 mixing by an external magnetic field are considered. An analytical expression for the stationary rate constant is obtained from which appropriate conditions for experimental investigations are predicted.

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540 Chemie

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ISO 690GORELIK, Elena V., Nikita N. LUKZEN, Renad Z. SAGDEEV, Ulrich STEINER, 2000. Application of integral encounter theory to account for the spin effects in radical reactions (I) : g and spin relaxation effects on recombination kinetics of free radicals. In: Chemical Physics. 2000, 262(2-3), pp. 303-323. ISSN 0301-0104. Available under: doi: 10.1016/S0301-0104(00)00312-8
BibTex
@article{Gorelik2000Appli-10032,
  year={2000},
  doi={10.1016/S0301-0104(00)00312-8},
  title={Application of integral encounter theory to account for the spin effects in radical reactions (I) : g and spin relaxation effects on recombination kinetics of free radicals},
  number={2-3},
  volume={262},
  issn={0301-0104},
  journal={Chemical Physics},
  pages={303--323},
  author={Gorelik, Elena V. and Lukzen, Nikita N. and Sagdeev, Renad Z. and Steiner, Ulrich}
}
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