Publikation: The synthesis, structures, and electrochemistry of 1′-heteroaryl-2,5-dimethylazaferrocenes
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2008
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Kowalski, Konrad
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Published
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Journal of Organometallic Chemistry. 2008, 693(12), pp. 2181-2187. ISSN 0022-328X. Available under: doi: 10.1016/j.jorganchem.2008.03.012
Zusammenfassung
We report the synthesis of 1′-heteroaryl-2,5-dimethylazaferrocenes (heteroaryl = 2-bromothiophen-5-yl and 2-bromopyrid-6-yl) via palladium catalysed cross-coupling reactions along with their crystallographically determined structures. The newly synthesized compounds as well as the parent 2,5-dimethylazaferrocene have been investigated by cyclic voltammetry (CV) and were found to exhibit reversible first oxidations followed by an irreversible oxidation at considerably higher potential.
Zusammenfassung in einer weiteren Sprache
Fachgebiet (DDC)
540 Chemie
Schlagwörter
Azaferrocene, Cross-coupling reaction, Cyclic voltammetry, X-ray diffraction
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WINTER, Rainer F., Konrad KOWALSKI, 2008. The synthesis, structures, and electrochemistry of 1′-heteroaryl-2,5-dimethylazaferrocenes. In: Journal of Organometallic Chemistry. 2008, 693(12), pp. 2181-2187. ISSN 0022-328X. Available under: doi: 10.1016/j.jorganchem.2008.03.012BibTex
@article{Winter2008synth-13825, year={2008}, doi={10.1016/j.jorganchem.2008.03.012}, title={The synthesis, structures, and electrochemistry of 1′-heteroaryl-2,5-dimethylazaferrocenes}, number={12}, volume={693}, issn={0022-328X}, journal={Journal of Organometallic Chemistry}, pages={2181--2187}, author={Winter, Rainer F. and Kowalski, Konrad} }
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