Publikation:

The synthesis, structures, and electrochemistry of 1′-heteroaryl-2,5-dimethylazaferrocenes

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2008

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Kowalski, Konrad

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Published

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Journal of Organometallic Chemistry. 2008, 693(12), pp. 2181-2187. ISSN 0022-328X. Available under: doi: 10.1016/j.jorganchem.2008.03.012

Zusammenfassung

We report the synthesis of 1′-heteroaryl-2,5-dimethylazaferrocenes (heteroaryl = 2-bromothiophen-5-yl and 2-bromopyrid-6-yl) via palladium catalysed cross-coupling reactions along with their crystallographically determined structures. The newly synthesized compounds as well as the parent 2,5-dimethylazaferrocene have been investigated by cyclic voltammetry (CV) and were found to exhibit reversible first oxidations followed by an irreversible oxidation at considerably higher potential.

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Fachgebiet (DDC)
540 Chemie

Schlagwörter

Azaferrocene, Cross-coupling reaction, Cyclic voltammetry, X-ray diffraction

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ISO 690WINTER, Rainer F., Konrad KOWALSKI, 2008. The synthesis, structures, and electrochemistry of 1′-heteroaryl-2,5-dimethylazaferrocenes. In: Journal of Organometallic Chemistry. 2008, 693(12), pp. 2181-2187. ISSN 0022-328X. Available under: doi: 10.1016/j.jorganchem.2008.03.012
BibTex
@article{Winter2008synth-13825,
  year={2008},
  doi={10.1016/j.jorganchem.2008.03.012},
  title={The synthesis, structures, and electrochemistry of 1′-heteroaryl-2,5-dimethylazaferrocenes},
  number={12},
  volume={693},
  issn={0022-328X},
  journal={Journal of Organometallic Chemistry},
  pages={2181--2187},
  author={Winter, Rainer F. and Kowalski, Konrad}
}
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