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On the role of block copolymer additives for calcium carbonate crystallization : Small angle neutron scattering investigation by applying contrast variation

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2004

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Endo, Hitoshi
Schwahn, Dietmar

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The Journal of Chemical Physics. 2004, 120(19), pp. 9410-9423. ISSN 0021-9606. eISSN 1089-7690. Available under: doi: 10.1063/1.1691736

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The role of the double-hydrophilic block copolymer poly(ethylen glycol)-block-poly(methacrylic acid) (PEG-b-PMAA) on the morphogenesis of calcium carbonate (CaCO3) was studied by applying the contrast variation small angle neutron scattering technique. The morphology and size of CaCO3 crystals is strongly affected by the addition of PEG-b-PMAA. In order to determine the partial scattering functions of the polymer and CaCO3 mineral, we developed both an experimental and theoretical approach with a sophisticated method of their determination from the scattering intensity. Partial scattering functions give detailed information for each component. In particular, the partial scattering function of the polymer, Spp, shows a monotonic slope with Q-2 to -3 where the scattering vector Q is low (Q < 0.01 Angstrom-1), which is a clear evidence that the polymer within the CaCO3 mineral has a mass fractal dimension. The other partial scattering functions reflected the geometry of the CaCO3 particles or the "interaction" of polymer and CaCO3 on a microscopic scale, which leads to a coherent view with Spp.

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ISO 690ENDO, Hitoshi, Dietmar SCHWAHN, Helmut CÖLFEN, 2004. On the role of block copolymer additives for calcium carbonate crystallization : Small angle neutron scattering investigation by applying contrast variation. In: The Journal of Chemical Physics. 2004, 120(19), pp. 9410-9423. ISSN 0021-9606. eISSN 1089-7690. Available under: doi: 10.1063/1.1691736
BibTex
@article{Endo2004-05-15block-40454,
  year={2004},
  doi={10.1063/1.1691736},
  title={On the role of block copolymer additives for calcium carbonate crystallization : Small angle neutron scattering investigation by applying contrast variation},
  number={19},
  volume={120},
  issn={0021-9606},
  journal={The Journal of Chemical Physics},
  pages={9410--9423},
  author={Endo, Hitoshi and Schwahn, Dietmar and Cölfen, Helmut}
}
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    <dcterms:abstract xml:lang="eng">The role of the double-hydrophilic block copolymer poly(ethylen glycol)-block-poly(methacrylic acid) (PEG-b-PMAA) on the morphogenesis of calcium carbonate (CaCO&lt;sub&gt;3&lt;/sub&gt;) was studied by applying the contrast variation small angle neutron scattering technique. The morphology and size of CaCO&lt;sub&gt;3&lt;/sub&gt; crystals is strongly affected by the addition of PEG-b-PMAA. In order to determine the partial scattering functions of the polymer and CaCO&lt;sub&gt;3&lt;/sub&gt; mineral, we developed both an experimental and theoretical approach with a sophisticated method of their determination from the scattering intensity. Partial scattering functions give detailed information for each component. In particular, the partial scattering function of the polymer, Spp, shows a monotonic slope with Q&lt;sup&gt;-2 to -3&lt;/sup&gt; where the scattering vector Q is low (Q &lt; 0.01 Angstrom&lt;sup&gt;-1&lt;/sup&gt;), which is a clear evidence that the polymer within the CaCO&lt;sub&gt;3&lt;/sub&gt; mineral has a mass fractal dimension. The other partial scattering functions reflected the geometry of the CaCO&lt;sub&gt;3&lt;/sub&gt; particles or the "interaction" of polymer and CaCO&lt;sub&gt;3&lt;/sub&gt; on a microscopic scale, which leads to a coherent view with S&lt;sub&gt;pp&lt;/sub&gt;.</dcterms:abstract>
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