On the Way to Heptahexaenylidene Complexes :  Trapping of an Intermediate with the Novel M=C=C=C=C=C=C=CR2 Moiety

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dc.contributor.authorRoth, Gerharddeu
dc.contributor.authorFischer, Helmut
dc.date.accessioned2013-06-12T10:43:42Zdeu
dc.date.available2013-06-12T10:43:42Zdeu
dc.date.issued1996
dc.description.abstractSequential treatment of the in situ generated heptatriyne Me3SiCCCCCCC(NMe2)3 with n-BuLi, (CO)5W[THF], and BF3·OEt2 affords the first alkenyl-substituted pentatetraenylidene complex, (CO)5WC CCCC(NMe2)C(H)C(NMe2)2 (4), via addition of dimethylamine to the CεCζ bond of the intermediate heptahexaenylidene complex (CO)5WCαCβCγCδ CεCζCη(NMe2)2. In addition, the alkynyl(butatrienyl)carbene complex (CO)5WC(CCSiMe3)C(Bu)C CC(NMe2)2 (5) is formed.eng
dc.description.versionpublished
dc.identifier.citationOrganometallics ; 15 (1996), 26. - S. 5766–5768deu
dc.identifier.doi10.1021/om960605xdeu
dc.identifier.urihttp://kops.uni-konstanz.de/handle/123456789/23056
dc.language.isoengdeu
dc.legacy.dateIssued2013-06-12deu
dc.rightsterms-of-usedeu
dc.rights.urihttps://rightsstatements.org/page/InC/1.0/deu
dc.subject.ddc540deu
dc.titleOn the Way to Heptahexaenylidene Complexes :  Trapping of an Intermediate with the Novel M=C=C=C=C=C=C=CR2 Moietyeng
dc.typeJOURNAL_ARTICLEdeu
dspace.entity.typePublication
kops.citation.bibtex
@article{Roth1996Hepta-23056,
  year={1996},
  doi={10.1021/om960605x},
  title={On the Way to Heptahexaenylidene Complexes :  Trapping of an Intermediate with the Novel M=C=C=C=C=C=C=CR2 Moiety},
  number={26},
  volume={15},
  issn={0276-7333},
  journal={Organometallics},
  pages={5766--5768},
  author={Roth, Gerhard and Fischer, Helmut}
}
kops.citation.iso690ROTH, Gerhard, Helmut FISCHER, 1996. On the Way to Heptahexaenylidene Complexes :  Trapping of an Intermediate with the Novel M=C=C=C=C=C=C=CR2 Moiety. In: Organometallics. 1996, 15(26), pp. 5766-5768. ISSN 0276-7333. eISSN 1520-6041. Available under: doi: 10.1021/om960605xdeu
kops.citation.iso690ROTH, Gerhard, Helmut FISCHER, 1996. On the Way to Heptahexaenylidene Complexes :  Trapping of an Intermediate with the Novel M=C=C=C=C=C=C=CR2 Moiety. In: Organometallics. 1996, 15(26), pp. 5766-5768. ISSN 0276-7333. eISSN 1520-6041. Available under: doi: 10.1021/om960605xeng
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    <dcterms:abstract xml:lang="eng">Sequential treatment of the in situ generated heptatriyne Me3SiCCCCCCC(NMe2)3 with n-BuLi, (CO)5W[THF], and BF3·OEt2 affords the first alkenyl-substituted pentatetraenylidene complex, (CO)5WC CCCC(NMe2)C(H)C(NMe2)2 (4), via addition of dimethylamine to the CεCζ bond of the intermediate heptahexaenylidene complex (CO)5WCαCβCγCδ CεCζCη(NMe2)2. In addition, the alkynyl(butatrienyl)carbene complex (CO)5WC(CCSiMe3)C(Bu)C CC(NMe2)2 (5) is formed.</dcterms:abstract>
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kops.sourcefieldOrganometallics. 1996, <b>15</b>(26), pp. 5766-5768. ISSN 0276-7333. eISSN 1520-6041. Available under: doi: 10.1021/om960605xdeu
kops.sourcefield.plainOrganometallics. 1996, 15(26), pp. 5766-5768. ISSN 0276-7333. eISSN 1520-6041. Available under: doi: 10.1021/om960605xdeu
kops.sourcefield.plainOrganometallics. 1996, 15(26), pp. 5766-5768. ISSN 0276-7333. eISSN 1520-6041. Available under: doi: 10.1021/om960605xeng
kops.submitter.emailkarin.hoch@uni-konstanz.dedeu
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source.periodicalTitleOrganometallics

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