IR studies at elevated gas pressures III. Kinetics of the CO induced disproportionation of (C5(CH3)5)2TiX (X = Cl, Br, I)

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dc.contributor.authorLuinstra, Gerrit A.deu
dc.contributor.authorTeuben, Jan H.deu
dc.contributor.authorBrintzinger, Hans-Herbert
dc.date.accessioned2013-08-12T08:38:58Zdeu
dc.date.available2013-08-12T08:38:58Zdeu
dc.date.issued1989
dc.description.abstractThe disproportionation of Cp2★TiClCO (Cp★ = η5-C5(CH3)5) (formed from Cp2★TiCl and CO in toluene solution) into Cp2★TiCl2 and Cp2★Ti(CO)2 has been studied at CO pressures of between 2 and 90 bar. The rate of reaction was found to be inversely proportional to the CO concentration. The reaction order with respect to Cp2★TiClCO changed from 1 to 1.4 with increasing CO pressure. The observations are explained in terms of a kinetic scheme in which Cp2★TiCl, which is formed from Cp2★TiClCO in a slow reaction, is an essential intermediate.eng
dc.description.versionpublished
dc.identifier.citationJournal of Organometallic Chemistry ; 375 (1989), 2. - S. 183-190deu
dc.identifier.doi10.1016/0022-328X(89)85112-5deu
dc.identifier.ppn392161907deu
dc.identifier.urihttp://kops.uni-konstanz.de/handle/123456789/23956
dc.language.isoengdeu
dc.legacy.dateIssued2013-08-12deu
dc.rightsterms-of-usedeu
dc.rights.urihttps://rightsstatements.org/page/InC/1.0/deu
dc.subject.ddc540deu
dc.titleIR studies at elevated gas pressures III. Kinetics of the CO induced disproportionation of (C<sub>5</sub>(CH<sub>3</sub>)<sub>5</sub>)<sub>2</sub>TiX (X = Cl, Br, I)eng
dc.typeJOURNAL_ARTICLEdeu
dspace.entity.typePublication
kops.citation.bibtex
@article{Luinstra1989studi-23956,
  year={1989},
  doi={10.1016/0022-328X(89)85112-5},
  title={IR studies at elevated gas pressures III. Kinetics of the CO induced disproportionation of (C<sub>5</sub>(CH<sub>3</sub>)<sub>5</sub>)<sub>2</sub>TiX (X = Cl, Br, I)},
  number={2},
  volume={375},
  issn={0022-328X},
  journal={Journal of Organometallic Chemistry},
  pages={183--190},
  author={Luinstra, Gerrit A. and Teuben, Jan H. and Brintzinger, Hans-Herbert}
}
kops.citation.iso690LUINSTRA, Gerrit A., Jan H. TEUBEN, Hans-Herbert BRINTZINGER, 1989. IR studies at elevated gas pressures III. Kinetics of the CO induced disproportionation of (C5(CH3)5)2TiX (X = Cl, Br, I). In: Journal of Organometallic Chemistry. 1989, 375(2), pp. 183-190. ISSN 0022-328X. eISSN 1872-8561. Available under: doi: 10.1016/0022-328X(89)85112-5deu
kops.citation.iso690LUINSTRA, Gerrit A., Jan H. TEUBEN, Hans-Herbert BRINTZINGER, 1989. IR studies at elevated gas pressures III. Kinetics of the CO induced disproportionation of (C5(CH3)5)2TiX (X = Cl, Br, I). In: Journal of Organometallic Chemistry. 1989, 375(2), pp. 183-190. ISSN 0022-328X. eISSN 1872-8561. Available under: doi: 10.1016/0022-328X(89)85112-5eng
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    <dcterms:abstract xml:lang="eng">The disproportionation of Cp&lt;sub&gt;2&lt;/sub&gt;★TiClCO (Cp★ = η&lt;sup&gt;5&lt;/sup&gt;-C&lt;sub&gt;5&lt;/sub&gt;(CH&lt;sub&gt;3&lt;/sub&gt;)&lt;sub&gt;5&lt;/sub&gt;) (formed from Cp&lt;sub&gt;2&lt;/sub&gt;★TiCl and CO in toluene solution) into Cp&lt;sub&gt;2&lt;/sub&gt;★TiCl2 and Cp2★Ti(CO)&lt;sub&gt;2&lt;/sub&gt; has been studied at CO pressures of between 2 and 90 bar. The rate of reaction was found to be inversely proportional to the CO concentration. The reaction order with respect to Cp&lt;sub&gt;2&lt;/sub&gt;★TiClCO changed from 1 to 1.4 with increasing CO pressure. The observations are explained in terms of a kinetic scheme in which Cp&lt;sub&gt;2&lt;/sub&gt;★TiCl, which is formed from Cp&lt;sub&gt;2&lt;/sub&gt;★TiClCO in a slow reaction, is an essential intermediate.</dcterms:abstract>
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kops.description.openAccessopenaccessgreen
kops.identifier.nbnurn:nbn:de:bsz:352-239565deu
kops.sourcefieldJournal of Organometallic Chemistry. 1989, <b>375</b>(2), pp. 183-190. ISSN 0022-328X. eISSN 1872-8561. Available under: doi: 10.1016/0022-328X(89)85112-5deu
kops.sourcefield.plainJournal of Organometallic Chemistry. 1989, 375(2), pp. 183-190. ISSN 0022-328X. eISSN 1872-8561. Available under: doi: 10.1016/0022-328X(89)85112-5deu
kops.sourcefield.plainJournal of Organometallic Chemistry. 1989, 375(2), pp. 183-190. ISSN 0022-328X. eISSN 1872-8561. Available under: doi: 10.1016/0022-328X(89)85112-5eng
kops.submitter.emailoleg.kozlov@uni-konstanz.dedeu
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source.bibliographicInfo.toPage190
source.bibliographicInfo.volume375
source.identifier.eissn1872-8561deu
source.identifier.issn0022-328X
source.periodicalTitleJournal of Organometallic Chemistry

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