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Formation of allylsilanes from Cl2[P(C6H11)3]2Ru[double bond, length half m-dash]C(R)H and vinylsilanes—β-SiR′3 elimination from ruthenacyclobutanes as a terminating step in olefin cross-metathesis

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2000

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Pietraszuk, Cezary

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http://nbn-resolving.de/urn:nbn:de:bsz:352-229665
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https://doi.org/10.1039/B008536G
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Chemical Communications. 2000(24), pp. 2463-2464. ISSN 1359-7345. eISSN 1364-548X. Available under: doi: 10.1039/B008536G

Zusammenfassung

Stoichiometric reactions of the Grubbs carbene complex [Cl2{P(C6H11)3} 2Ru[double bond, length half m-dash]C(Ph)H] with vinylsilanes, H2C[double bond, length half m-dash]C(SiMenR3−n )H (R = Ph, OEt; n = 1, 2, 3), afford metathesis products and allylsilanes formed by β-SiR3 elimination followed by reductive elimination; the formation of allylsilanes constitutes a terminating step in the Ru-catalysed cross-metathesis of olefins with methylsubstituted vinylsilanes.

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540 Chemie

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ISO 690PIETRASZUK, Cezary, Helmut FISCHER, 2000. Formation of allylsilanes from Cl2[P(C6H11)3]2Ru[double bond, length half m-dash]C(R)H and vinylsilanes—β-SiR′3 elimination from ruthenacyclobutanes as a terminating step in olefin cross-metathesis. In: Chemical Communications. 2000(24), pp. 2463-2464. ISSN 1359-7345. eISSN 1364-548X. Available under: doi: 10.1039/B008536G
BibTex
@article{Pietraszuk2000Forma-22966,
  year={2000},
  doi={10.1039/B008536G},
  title={Formation of allylsilanes from Cl2[P(C6H11)3]2Ru[double bond, length half m-dash]C(R)H and vinylsilanes—β-SiR′3 elimination from ruthenacyclobutanes as a terminating step in olefin cross-metathesis},
  number={24},
  issn={1359-7345},
  journal={Chemical Communications},
  pages={2463--2464},
  author={Pietraszuk, Cezary and Fischer, Helmut}
}
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    <dcterms:abstract xml:lang="eng">Stoichiometric reactions of the Grubbs carbene complex [Cl2{P(C6H11)3} 2Ru[double bond, length half m-dash]C(Ph)H] with vinylsilanes, H2C[double bond, length half m-dash]C(SiMenR3−n )H (R = Ph, OEt; n = 1, 2, 3), afford metathesis products and allylsilanes formed by β-SiR3 elimination followed by reductive elimination; the formation of allylsilanes constitutes a terminating step in the Ru-catalysed cross-metathesis of olefins with methylsubstituted vinylsilanes.</dcterms:abstract>
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