Formation of allylsilanes from Cl2[P(C6H11)3]2Ru[double bond, length half m-dash]C(R)H and vinylsilanes—β-SiR′3 elimination from ruthenacyclobutanes as a terminating step in olefin cross-metathesis

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dc.contributor.authorPietraszuk, Cezarydeu
dc.contributor.authorFischer, Helmut
dc.date.accessioned2013-06-05T09:25:52Zdeu
dc.date.available2013-06-05T09:25:52Zdeu
dc.date.issued2000
dc.description.abstractStoichiometric reactions of the Grubbs carbene complex [Cl2{P(C6H11)3} 2Ru[double bond, length half m-dash]C(Ph)H] with vinylsilanes, H2C[double bond, length half m-dash]C(SiMenR3−n )H (R = Ph, OEt; n = 1, 2, 3), afford metathesis products and allylsilanes formed by β-SiR3 elimination followed by reductive elimination; the formation of allylsilanes constitutes a terminating step in the Ru-catalysed cross-metathesis of olefins with methylsubstituted vinylsilanes.eng
dc.description.versionpublished
dc.identifier.citationChemical Communications ; (2000), 24. - S. 2463-2464deu
dc.identifier.doi10.1039/B008536Gdeu
dc.identifier.urihttp://kops.uni-konstanz.de/handle/123456789/22966
dc.language.isoengdeu
dc.legacy.dateIssued2013-06-05deu
dc.rightsterms-of-usedeu
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dc.subject.ddc540deu
dc.titleFormation of allylsilanes from Cl2[P(C6H11)3]2Ru[double bond, length half m-dash]C(R)H and vinylsilanes—β-SiR′3 elimination from ruthenacyclobutanes as a terminating step in olefin cross-metathesiseng
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@article{Pietraszuk2000Forma-22966,
  year={2000},
  doi={10.1039/B008536G},
  title={Formation of allylsilanes from Cl2[P(C6H11)3]2Ru[double bond, length half m-dash]C(R)H and vinylsilanes—β-SiR′3 elimination from ruthenacyclobutanes as a terminating step in olefin cross-metathesis},
  number={24},
  issn={1359-7345},
  journal={Chemical Communications},
  pages={2463--2464},
  author={Pietraszuk, Cezary and Fischer, Helmut}
}
kops.citation.iso690PIETRASZUK, Cezary, Helmut FISCHER, 2000. Formation of allylsilanes from Cl2[P(C6H11)3]2Ru[double bond, length half m-dash]C(R)H and vinylsilanes—β-SiR′3 elimination from ruthenacyclobutanes as a terminating step in olefin cross-metathesis. In: Chemical Communications. 2000(24), pp. 2463-2464. ISSN 1359-7345. eISSN 1364-548X. Available under: doi: 10.1039/B008536Gdeu
kops.citation.iso690PIETRASZUK, Cezary, Helmut FISCHER, 2000. Formation of allylsilanes from Cl2[P(C6H11)3]2Ru[double bond, length half m-dash]C(R)H and vinylsilanes—β-SiR′3 elimination from ruthenacyclobutanes as a terminating step in olefin cross-metathesis. In: Chemical Communications. 2000(24), pp. 2463-2464. ISSN 1359-7345. eISSN 1364-548X. Available under: doi: 10.1039/B008536Geng
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kops.sourcefieldChemical Communications. 2000(24), pp. 2463-2464. ISSN 1359-7345. eISSN 1364-548X. Available under: doi: 10.1039/B008536Gdeu
kops.sourcefield.plainChemical Communications. 2000(24), pp. 2463-2464. ISSN 1359-7345. eISSN 1364-548X. Available under: doi: 10.1039/B008536Gdeu
kops.sourcefield.plainChemical Communications. 2000(24), pp. 2463-2464. ISSN 1359-7345. eISSN 1364-548X. Available under: doi: 10.1039/B008536Geng
kops.submitter.emailkarin.hoch@uni-konstanz.dedeu
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