Phase Behavior of n-Alkyl-substituted Polysilanes
| dc.contributor.author | Mueller, Christian | |
| dc.contributor.author | Peter, Christine | |
| dc.contributor.author | Frey1, Holger | |
| dc.contributor.author | Schmidt, Claudia | |
| dc.date.accessioned | 2017-10-05T14:18:05Z | |
| dc.date.available | 2017-10-05T14:18:05Z | |
| dc.date.issued | 2003-09-26 | eng |
| dc.description.abstract | Polysilanes are high-molecular-weight polymers with a pure silicon chain as backbone and organic side chains. The σ-conjugation of the silicon backbone leads to interesting properties, such as strong UV absorption and photoconductivity. Poly(di-n-alkylsilanes) with n-alkyl side chains longer than ethyl form mesophases, in which the polymers are hexagonally packed in two dimensions but have highly flexible backbones. Such condis (conformationally disordered) crystals, characterized by a dynamic exchange between different conformations, are also known for other polymers, for example, polysiloxanes and polyphosphazenes. A clear proof of the backbone mobility in these mesophases is provided by solid-state NMR spectroscopy. | eng |
| dc.description.version | published | eng |
| dc.identifier.doi | 10.1002/9783527610761.ch12 | eng |
| dc.identifier.uri | https://kops.uni-konstanz.de/handle/123456789/40250 | |
| dc.language.iso | eng | eng |
| dc.subject.ddc | 540 | eng |
| dc.title | Phase Behavior of n-Alkyl-substituted Polysilanes | eng |
| dc.type | INCOLLECTION | eng |
| dspace.entity.type | Publication | |
| kops.citation.bibtex | @incollection{Mueller2003-09-26Phase-40250,
year={2003},
doi={10.1002/9783527610761.ch12},
title={Phase Behavior of n-Alkyl-substituted Polysilanes},
isbn={978-3-527-30647-3},
publisher={Wiley-VCH},
address={Weinheim},
booktitle={Silicon Chemistry},
pages={159--170},
editor={Jutzi, Peter and Schubert, Ulrich},
author={Mueller, Christian and Peter, Christine and Frey1, Holger and Schmidt, Claudia}
} | |
| kops.citation.iso690 | MUELLER, Christian, Christine PETER, Holger FREY1, Claudia SCHMIDT, 2003. Phase Behavior of n-Alkyl-substituted Polysilanes. In: JUTZI, Peter, ed., Ulrich SCHUBERT, ed.. Silicon Chemistry. Weinheim: Wiley-VCH, 2003, pp. 159-170. ISBN 978-3-527-30647-3. Available under: doi: 10.1002/9783527610761.ch12 | deu |
| kops.citation.iso690 | MUELLER, Christian, Christine PETER, Holger FREY1, Claudia SCHMIDT, 2003. Phase Behavior of n-Alkyl-substituted Polysilanes. In: JUTZI, Peter, ed., Ulrich SCHUBERT, ed.. Silicon Chemistry. Weinheim: Wiley-VCH, 2003, pp. 159-170. ISBN 978-3-527-30647-3. Available under: doi: 10.1002/9783527610761.ch12 | eng |
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| kops.sourcefield | JUTZI, Peter, ed., Ulrich SCHUBERT, ed.. <i>Silicon Chemistry</i>. Weinheim: Wiley-VCH, 2003, pp. 159-170. ISBN 978-3-527-30647-3. Available under: doi: 10.1002/9783527610761.ch12 | deu |
| kops.sourcefield.plain | JUTZI, Peter, ed., Ulrich SCHUBERT, ed.. Silicon Chemistry. Weinheim: Wiley-VCH, 2003, pp. 159-170. ISBN 978-3-527-30647-3. Available under: doi: 10.1002/9783527610761.ch12 | deu |
| kops.sourcefield.plain | JUTZI, Peter, ed., Ulrich SCHUBERT, ed.. Silicon Chemistry. Weinheim: Wiley-VCH, 2003, pp. 159-170. ISBN 978-3-527-30647-3. Available under: doi: 10.1002/9783527610761.ch12 | eng |
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| source.contributor.editor | Jutzi, Peter | |
| source.contributor.editor | Schubert, Ulrich | |
| source.identifier.isbn | 978-3-527-30647-3 | eng |
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| source.publisher.location | Weinheim | eng |
| source.title | Silicon Chemistry | eng |