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Highly conductive molecular junctions based on direct binding of benzene to Platinum electrodes

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kiguchi_212064.pdf
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2008

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Kiguchi, Manabu
Tal, Oren
Wohlthat, Sören
Krieger, Michael
Djukic, Darko
Ruitenbeek, Jan M.

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Physical Review Letters. 2008, 101(4). ISSN 0031-9007. eISSN 1079-7114. Available under: doi: 10.1103/PhysRevLett.101.046801

Zusammenfassung

Highly conductive molecular junctions were formed by direct binding of benzene molecules between two Pt electrodes. Measurements of conductance, isotopic shift in inelastic spectroscopy, and shot noise compared with calculations provide indications for a stable molecular junction where the benzene molecule is preserved intact and bonded to the Pt leads via carbon atoms. The junction has a conductance comparable to that for metallic atomic junctions (around 0.1–1G0), where the conductance and the number of transmission channels are controlled by the molecule's orientation at different interelectrode distances.

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ISO 690KIGUCHI, Manabu, Oren TAL, Sören WOHLTHAT, Fabian PAULY, Michael KRIEGER, Darko DJUKIC, Juan Carlos CUEVAS, Jan M. RUITENBEEK, 2008. Highly conductive molecular junctions based on direct binding of benzene to Platinum electrodes. In: Physical Review Letters. 2008, 101(4). ISSN 0031-9007. eISSN 1079-7114. Available under: doi: 10.1103/PhysRevLett.101.046801
BibTex
@article{Kiguchi2008Highl-21206,
  year={2008},
  doi={10.1103/PhysRevLett.101.046801},
  title={Highly conductive molecular junctions based on direct binding of benzene to Platinum electrodes},
  number={4},
  volume={101},
  issn={0031-9007},
  journal={Physical Review Letters},
  author={Kiguchi, Manabu and Tal, Oren and Wohlthat, Sören and Pauly, Fabian and Krieger, Michael and Djukic, Darko and Cuevas, Juan Carlos and Ruitenbeek, Jan M.}
}
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