Publikation:

Water-Soluble Salicylaldiminato Ni (II)-Methyl Complexes : Enhanced Dissociative Activation for Ethylene Polymerization with Unprecedented Nanoparticle Formation

Vorschaubild

Dateien

Supporting_information_Water_Soluble_Salicylaldiminato_Ni.pdf
Supporting_information_Water_Soluble_Salicylaldiminato_Ni.pdfGröße: 1.27 MBDownloads: 463
Water_Soluble_Salicylaldiminato_Ni.pdf
Water_Soluble_Salicylaldiminato_Ni.pdfGröße: 50.29 KBDownloads: 143

Datum

2006

Autor:innen

Herausgeber:innen

Kontakt

ISSN der Zeitschrift

Electronic ISSN

ISBN

Bibliografische Daten

Verlag

Schriftenreihe

Auflagebezeichnung

URI (zitierfähiger Link)
http://nbn-resolving.de/urn:nbn:de:bsz:352-opus-65883
DOI (zitierfähiger Link)
https://doi.org/10.1021/ja0619962
ArXiv-ID

Internationale Patentnummer

Link zur Lizenz
Attribution-NonCommercial-NoDerivs 2.0 Generic

Angaben zur Forschungsförderung

Projekt

Open Access-Veröffentlichung
Open Access Green

Sammlungen

Chemie: Publikationen
Core Facility der Universität Konstanz

Gesperrt bis

Titel in einer weiteren Sprache

Publikationstyp
Zeitschriftenartikel
Publikationsstatus
Published

Erschienen in

Journal of the American Chemical Society. 2006, 128(24), pp. 7708-7709. ISSN 0002-7863. eISSN 1520-5126. Available under: doi: 10.1021/ja0619962

Zusammenfassung

Water-soluble single-component (kappa2-N,O)-salicylaldiminato nickel-methyl complexes 1-4-L (L = TPPTS, TPPDS, H2N-PEG-OMe) allow for the catalytic polymerization of ethylene under organic solvent-free aqueous conditions producing high molecular weight polyethylene with particle sizes below 10 nm. Amphiphilic TPPDS- and H2N-PEG-OMe complexes exhibit a polymerization activity in water higher than that in toluene. A solvation-favored activation of precatalysts 1-4-L by equilibrium dissociation of L in aqueous solution likely accounts for this enhanced polymerization activity. The observed generation of a given particle by a single active site is an unprecedented mechanism for formation of aqueous particle dispersions.

Zusammenfassung in einer weiteren Sprache

Fachgebiet (DDC)
540 Chemie

Schlagwörter

Konferenz

Rezension
undefined / . - undefined, undefined

Forschungsvorhaben

Organisationseinheiten

Zeitschriftenheft

Zugehörige Datensätze in KOPS

Zitieren

ISO 690GÖTTKER-SCHNETMANN, Inigo, Brigitte KORTHALS, Stefan MECKING, 2006. Water-Soluble Salicylaldiminato Ni (II)-Methyl Complexes : Enhanced Dissociative Activation for Ethylene Polymerization with Unprecedented Nanoparticle Formation. In: Journal of the American Chemical Society. 2006, 128(24), pp. 7708-7709. ISSN 0002-7863. eISSN 1520-5126. Available under: doi: 10.1021/ja0619962
BibTex
@article{GottkerSchnetmann2006Water-9845,
  year={2006},
  doi={10.1021/ja0619962},
  title={Water-Soluble Salicylaldiminato Ni (II)-Methyl Complexes : Enhanced Dissociative Activation for Ethylene Polymerization with Unprecedented Nanoparticle Formation},
  number={24},
  volume={128},
  issn={0002-7863},
  journal={Journal of the American Chemical Society},
  pages={7708--7709},
  author={Göttker-Schnetmann, Inigo and Korthals, Brigitte and Mecking, Stefan}
}
RDF
<rdf:RDF
    xmlns:dcterms="http://purl.org/dc/terms/"
    xmlns:dc="http://purl.org/dc/elements/1.1/"
    xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#"
    xmlns:bibo="http://purl.org/ontology/bibo/"
    xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#"
    xmlns:foaf="http://xmlns.com/foaf/0.1/"
    xmlns:void="http://rdfs.org/ns/void#"
    xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > 
  <rdf:Description rdf:about="https://kops.uni-konstanz.de/server/rdf/resource/123456789/9845">
    <dc:rights>Attribution-NonCommercial-NoDerivs 2.0 Generic</dc:rights>
    <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/9845"/>
    <dc:contributor>Göttker-Schnetmann, Inigo</dc:contributor>
    <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T18:14:49Z</dc:date>
    <dcterms:hasPart rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/9845/1/Supporting_information_Water_Soluble_Salicylaldiminato_Ni.pdf"/>
    <dc:creator>Korthals, Brigitte</dc:creator>
    <dcterms:abstract>Water-soluble single-component (kappa2-N,O)-salicylaldiminato nickel-methyl complexes 1-4-L (L = TPPTS, TPPDS, H2N-PEG-OMe) allow for the catalytic polymerization of ethylene under organic solvent-free aqueous conditions producing high molecular weight polyethylene with particle sizes below 10 nm. Amphiphilic TPPDS- and H2N-PEG-OMe complexes exhibit a polymerization activity in water higher than that in toluene. A solvation-favored activation of precatalysts 1-4-L by equilibrium dissociation of L in aqueous solution likely accounts for this enhanced polymerization activity. The observed generation of a given particle by a single active site is an unprecedented mechanism for formation of aqueous particle dispersions.</dcterms:abstract>
    <dc:creator>Göttker-Schnetmann, Inigo</dc:creator>
    <dcterms:hasPart rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/9845/2/Water_Soluble_Salicylaldiminato_Ni.pdf"/>
    <dcterms:title>Water-Soluble Salicylaldiminato Ni (II)-Methyl Complexes : Enhanced Dissociative Activation for Ethylene Polymerization with Unprecedented Nanoparticle Formation</dcterms:title>
    <void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/>
    <dc:creator>Mecking, Stefan</dc:creator>
    <dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/>
    <dspace:hasBitstream rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/9845/1/Supporting_information_Water_Soluble_Salicylaldiminato_Ni.pdf"/>
    <dspace:hasBitstream rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/9845/2/Water_Soluble_Salicylaldiminato_Ni.pdf"/>
    <dc:contributor>Mecking, Stefan</dc:contributor>
    <dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/>
    <dc:format>application/pdf</dc:format>
    <dcterms:issued>2006</dcterms:issued>
    <dc:contributor>Korthals, Brigitte</dc:contributor>
    <dcterms:rights rdf:resource="http://creativecommons.org/licenses/by-nc-nd/2.0/"/>
    <dcterms:bibliographicCitation>First publ. in: Journal of the American Chemical Society ; 128 (2006), 24. - S. 7708-7709</dcterms:bibliographicCitation>
    <dc:language>eng</dc:language>
    <foaf:homepage rdf:resource="http://localhost:8080/"/>
  </rdf:Description>
</rdf:RDF>

Interner Vermerk

xmlui.Submission.submit.DescribeStep.inputForms.label.kops_note_fromSubmitter

Kontakt
URL der Originalveröffentl.

Prüfdatum der URL

Prüfungsdatum der Dissertation

Finanzierungsart

Kommentar zur Publikation

Allianzlizenz
Corresponding Authors der Uni Konstanz vorhanden
Internationale Co-Autor:innen
Universitätsbibliographie
Ja
Begutachtet
Diese Publikation teilen