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Stearate-Coated Biogenic Calcium Carbonate from Waste Seashells : A Sustainable Plastic Filler

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2024

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Basile, Maria Luisa
Triunfo, Carla
Fermani, Simona
Laurenzi, Davide
Maoloni, Gabriele
Mazzon, Martina
Marzadori, Claudio
Falini, Giuseppe
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ACS Omega. ACS Publications. 2024, 9(10), S. 11232-11242. eISSN 2470-1343. Verfügbar unter: doi: 10.1021/acsomega.3c06186

Zusammenfassung

Waste seashells from aquaculture are a massive source of biogenic calcium carbonate (bCC) that can be a potential substitute for ground calcium carbonate and precipitated calcium carbonate. These last materials find several applications in industry after a surface coating with hydrophobic molecules, with stearate as the most used. Here, we investigate for the first time the capability of aqueous stearate dispersions to coat bCC powders from seashells of market-relevant mollusc aquaculture species, namely the oyster Crassostrea gigas, the scallop Pecten jacobaeus, and the clam Chamelea gallina. The chemical–physical features of bCC were extensively characterized by different analytical techniques. The results of stearate adsorption experiments showed that the oyster shell powder, which is the bCC with a higher content of the organic matrix, showed the highest adsorption capability (about 23 wt % compared to 10 wt % of geogenic calcite). These results agree with the mechanism proposed in the literature in which stearate adsorption mainly involves the formation of calcium stearate micelles in the dispersion before the physical adsorption. The coated bCC from oyster shells was also tested as fillers in an ethylene vinyl acetate compound used for the preparation of shoe soles. The obtained compound showed better mechanical performance than the one prepared using ground calcium. In conclusion, we can state that bCC can replace ground and precipitated calcium carbonate and has a higher stearate adsorbing capability. Moreover, they represent an environmentally friendly and sustainable source of calcium carbonate that organisms produce by high biological control over composition, polymorphism, and crystal texture. These features can be exploited for applications in fields where calcium carbonate with selected features is required.

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ISO 690BASILE, Maria Luisa, Carla TRIUNFO, Stefanie GÄRTNER, Simona FERMANI, Davide LAURENZI, Gabriele MAOLONI, Martina MAZZON, Claudio MARZADORI, Helmut CÖLFEN, Giuseppe FALINI, 2024. Stearate-Coated Biogenic Calcium Carbonate from Waste Seashells : A Sustainable Plastic Filler. In: ACS Omega. ACS Publications. 2024, 9(10), S. 11232-11242. eISSN 2470-1343. Verfügbar unter: doi: 10.1021/acsomega.3c06186
BibTex
@article{Basile2024Stear-69909,
  year={2024},
  doi={10.1021/acsomega.3c06186},
  title={Stearate-Coated Biogenic Calcium Carbonate from Waste Seashells : A Sustainable Plastic Filler},
  number={10},
  volume={9},
  journal={ACS Omega},
  pages={11232--11242},
  author={Basile, Maria Luisa and Triunfo, Carla and Gärtner, Stefanie and Fermani, Simona and Laurenzi, Davide and Maoloni, Gabriele and Mazzon, Martina and Marzadori, Claudio and Cölfen, Helmut and Falini, Giuseppe}
}
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