Synthesis and properties of highly branched polycations with an aliphatic polyether scaffold

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dc.contributor.authorSchwab, Ernstdeu
dc.contributor.authorMecking, Stefan
dc.date.accessioned2011-03-24T18:14:24Zdeu
dc.date.available2011-03-24T18:14:24Zdeu
dc.date.issued2005deu
dc.description.abstractCationic polyelectrolytes with pyridinium and 1,2-dimethylimidazolium functionalities based on a hyperbranched polyglycerol scaffold with a narrow polydispersit were prepared by a polymer analogous reaction in a one-pot synthesis. By the variation of the spacer lengths between the cationic functionalities and polyether scaffold, a simple method was developed to adjust the charge density and flexibility of the polycations, as reflected by their glass-transition temperature. The polyelectrolytes were further characterized in detail by 1H NMR, 13C NMR, and IR spectroscopy, as well as thermogravimetric analysis.eng
dc.description.versionpublished
dc.format.mimetypeapplication/pdfdeu
dc.identifier.citationFirst publ. in: Journal of Polymer Science / A, Polymer Chemistry, 43 (2005), pp. 4609-4617deu
dc.identifier.doi10.1002/pola.20983
dc.identifier.ppn274557339deu
dc.identifier.urihttp://kops.uni-konstanz.de/handle/123456789/9787
dc.language.isoengdeu
dc.legacy.dateIssued2007deu
dc.rightsAttribution-NonCommercial-NoDerivs 2.0 Generic
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/2.0/
dc.subjectfunctionalization of polymersdeu
dc.subjecthyperbrancheddeu
dc.subjectpolyelectrolytesdeu
dc.subject.ddc540deu
dc.titleSynthesis and properties of highly branched polycations with an aliphatic polyether scaffoldeng
dc.typeJOURNAL_ARTICLEdeu
dspace.entity.typePublication
kops.citation.bibtex
@article{Schwab2005Synth-9787,
  year={2005},
  doi={10.1002/pola.20983},
  title={Synthesis and properties of highly branched polycations with an aliphatic polyether scaffold},
  number={19},
  volume={43},
  issn={0887-624X},
  journal={Journal of Polymer Science / A, Polymer Chemistry},
  pages={4609--4617},
  author={Schwab, Ernst and Mecking, Stefan}
}
kops.citation.iso690SCHWAB, Ernst, Stefan MECKING, 2005. Synthesis and properties of highly branched polycations with an aliphatic polyether scaffold. In: Journal of Polymer Science / A, Polymer Chemistry. 2005, 43(19), pp. 4609-4617. ISSN 0887-624X. eISSN 1099-0518. Available under: doi: 10.1002/pola.20983deu
kops.citation.iso690SCHWAB, Ernst, Stefan MECKING, 2005. Synthesis and properties of highly branched polycations with an aliphatic polyether scaffold. In: Journal of Polymer Science / A, Polymer Chemistry. 2005, 43(19), pp. 4609-4617. ISSN 0887-624X. eISSN 1099-0518. Available under: doi: 10.1002/pola.20983eng
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