[2+2+2]-Cycloaddition of 4-Hydroxy-Substituted Enediynes to 2-Hydroxy-Substituted Decahydrophenanthrenes

Groth, Ulrich; Richter, Norbert; Kalogerakis, Aris

[2+2+2]-Cycloaddition of 4-Hydroxy-Substituted Enediynes to 2-Hydroxy-Substituted Decahydrophenanthrenes

Dateien

Groth_Cycloaddition_2003.pdf(161.09 KB)

Datum

2003

Autor:innen

Groth, Ulrich

Richter, Norbert

Kalogerakis, Aris

Publikationstyp

Zeitschriftenartikel

Erschienen in

European journal of organic chemistry ; 23 (2003). - S. 4634-4639

Zusammenfassung

Enediynes rac-4 were prepared in seven steps with an overall yield of 31% starting from 4-pentyn-1-ol (5). A cobalt mediated [2+2+2]-cycloaddition of these enediynes and subsequent removal of the metal fragment afforded the decahydrophenanthrenes rac-3/13 in 37-56% yield.

Fachgebiet (DDC)

540 Chemie

Schlagwörter

Cycloaddition,Cobalt,Zinc

Zitieren

ISO 690

GROTH, Ulrich, Norbert RICHTER, Aris KALOGERAKIS, 2003. [2+2+2]-Cycloaddition of 4-Hydroxy-Substituted Enediynes to 2-Hydroxy-Substituted Decahydrophenanthrenes. In: European journal of organic chemistry. 23, pp. 4634-4639. Available under: doi: 10.1002/ejoc.200300432

BibTex

@article{Groth2003222Cy-9688,
  year={2003},
  doi={10.1002/ejoc.200300432},
  title={[2+2+2]-Cycloaddition of 4-Hydroxy-Substituted Enediynes to 2-Hydroxy-Substituted Decahydrophenanthrenes},
  volume={23},
  journal={European journal of organic chemistry},
  pages={4634--4639},
  author={Groth, Ulrich and Richter, Norbert and Kalogerakis, Aris}
}

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