Zirconium Allyl Complexes as Participants in Zirconocene-Catalyzed α-Olefin Polymerizations
| dc.contributor.author | Babushkin, Dmitrii E. | |
| dc.contributor.author | Panchenko, Valentina N. | |
| dc.contributor.author | Brintzinger, Hans-Herbert | |
| dc.date.accessioned | 2014-11-27T10:15:59Z | |
| dc.date.available | 2014-11-27T10:15:59Z | |
| dc.date.issued | 2014 | eng |
| dc.description.abstract | In a search for the hitherto elusive catalyst resting state(s) of zirconocene-based olefin polymerization catalysts, a combination of UV/Vis and NMR spectrometric methods reveals that polymer-carrying cationic Zr allyl complexes make up about 90 % of the total catalyst concentration. Other catalyst species that take part in the polymerization process have to be generated from this allyl pool into which they appear to relapse rather frequently. | eng |
| dc.description.version | published | |
| dc.identifier.doi | 10.1002/anie.201403673 | eng |
| dc.identifier.uri | http://kops.uni-konstanz.de/handle/123456789/29332 | |
| dc.language.iso | eng | eng |
| dc.subject | allyl complexes, ansa-zirconocenes, olefin polymerization, polymerization catalysis, resting states | eng |
| dc.subject.ddc | 540 | eng |
| dc.title | Zirconium Allyl Complexes as Participants in Zirconocene-Catalyzed α-Olefin Polymerizations | eng |
| dc.type | JOURNAL_ARTICLE | eng |
| dspace.entity.type | Publication | |
| kops.citation.bibtex | @article{Babushkin2014Zirco-29332,
year={2014},
doi={10.1002/anie.201403673},
title={Zirconium Allyl Complexes as Participants in Zirconocene-Catalyzed α-Olefin Polymerizations},
number={36},
volume={53},
issn={0570-0833},
journal={Angewandte Chemie International Edition},
pages={9645--9649},
author={Babushkin, Dmitrii E. and Panchenko, Valentina N. and Brintzinger, Hans-Herbert}
} | |
| kops.citation.iso690 | BABUSHKIN, Dmitrii E., Valentina N. PANCHENKO, Hans-Herbert BRINTZINGER, 2014. Zirconium Allyl Complexes as Participants in Zirconocene-Catalyzed α-Olefin Polymerizations. In: Angewandte Chemie International Edition. 2014, 53(36), pp. 9645-9649. ISSN 0570-0833. eISSN 1521-3773. Available under: doi: 10.1002/anie.201403673 | deu |
| kops.citation.iso690 | BABUSHKIN, Dmitrii E., Valentina N. PANCHENKO, Hans-Herbert BRINTZINGER, 2014. Zirconium Allyl Complexes as Participants in Zirconocene-Catalyzed α-Olefin Polymerizations. In: Angewandte Chemie International Edition. 2014, 53(36), pp. 9645-9649. ISSN 0570-0833. eISSN 1521-3773. Available under: doi: 10.1002/anie.201403673 | eng |
| kops.citation.rdf | <rdf:RDF
xmlns:dcterms="http://purl.org/dc/terms/"
xmlns:dc="http://purl.org/dc/elements/1.1/"
xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#"
xmlns:bibo="http://purl.org/ontology/bibo/"
xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#"
xmlns:foaf="http://xmlns.com/foaf/0.1/"
xmlns:void="http://rdfs.org/ns/void#"
xmlns:xsd="http://www.w3.org/2001/XMLSchema#" >
<rdf:Description rdf:about="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29332">
<void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/>
<dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2014-11-27T10:15:59Z</dc:date>
<dc:creator>Babushkin, Dmitrii E.</dc:creator>
<bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/29332"/>
<dc:contributor>Panchenko, Valentina N.</dc:contributor>
<dcterms:issued>2014</dcterms:issued>
<dc:creator>Panchenko, Valentina N.</dc:creator>
<dc:creator>Brintzinger, Hans-Herbert</dc:creator>
<dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2014-11-27T10:15:59Z</dcterms:available>
<dc:language>eng</dc:language>
<dcterms:title>Zirconium Allyl Complexes as Participants in Zirconocene-Catalyzed α-Olefin Polymerizations</dcterms:title>
<dc:contributor>Brintzinger, Hans-Herbert</dc:contributor>
<dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/>
<dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/>
<foaf:homepage rdf:resource="http://localhost:8080/"/>
<dcterms:abstract xml:lang="eng">In a search for the hitherto elusive catalyst resting state(s) of zirconocene-based olefin polymerization catalysts, a combination of UV/Vis and NMR spectrometric methods reveals that polymer-carrying cationic Zr allyl complexes make up about 90 % of the total catalyst concentration. Other catalyst species that take part in the polymerization process have to be generated from this allyl pool into which they appear to relapse rather frequently.</dcterms:abstract>
<dc:contributor>Babushkin, Dmitrii E.</dc:contributor>
</rdf:Description>
</rdf:RDF> | |
| kops.sourcefield | Angewandte Chemie International Edition. 2014, <b>53</b>(36), pp. 9645-9649. ISSN 0570-0833. eISSN 1521-3773. Available under: doi: 10.1002/anie.201403673 | deu |
| kops.sourcefield.plain | Angewandte Chemie International Edition. 2014, 53(36), pp. 9645-9649. ISSN 0570-0833. eISSN 1521-3773. Available under: doi: 10.1002/anie.201403673 | deu |
| kops.sourcefield.plain | Angewandte Chemie International Edition. 2014, 53(36), pp. 9645-9649. ISSN 0570-0833. eISSN 1521-3773. Available under: doi: 10.1002/anie.201403673 | eng |
| relation.isAuthorOfPublication | ab4c86da-5c57-43c2-83ff-89fe2e461f70 | |
| relation.isAuthorOfPublication.latestForDiscovery | ab4c86da-5c57-43c2-83ff-89fe2e461f70 | |
| source.bibliographicInfo.fromPage | 9645 | eng |
| source.bibliographicInfo.issue | 36 | eng |
| source.bibliographicInfo.toPage | 9649 | eng |
| source.bibliographicInfo.volume | 53 | eng |
| source.identifier.eissn | 1521-3773 | eng |
| source.identifier.issn | 0570-0833 | eng |
| source.periodicalTitle | Angewandte Chemie International Edition | eng |
| temp.internal.duplicates | <p>Keine Dubletten gefunden. Letzte Überprüfung: 11.11.2014 12:28:54</p> | deu |