@article{Babushkin2014Zirco-29332,
  year={2014},
  doi={10.1002/anie.201403673},
  title={Zirconium Allyl Complexes as Participants in Zirconocene-Catalyzed α-Olefin Polymerizations},
  number={36},
  volume={53},
  issn={0570-0833},
  journal={Angewandte Chemie International Edition},
  pages={9645--9649},
  author={Babushkin, Dmitrii E. and Panchenko, Valentina N. and Brintzinger, Hans-Herbert}
}

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    <dc:creator>Babushkin, Dmitrii E.</dc:creator>
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    <dc:contributor>Panchenko, Valentina N.</dc:contributor>
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    <dc:creator>Brintzinger, Hans-Herbert</dc:creator>
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    <dcterms:title>Zirconium Allyl Complexes as Participants in Zirconocene-Catalyzed α-Olefin Polymerizations</dcterms:title>
    <dc:contributor>Brintzinger, Hans-Herbert</dc:contributor>
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    <dcterms:abstract xml:lang="eng">In a search for the hitherto elusive catalyst resting state(s) of zirconocene-based olefin polymerization catalysts, a combination of UV/Vis and NMR spectrometric methods reveals that polymer-carrying cationic Zr allyl complexes make up about 90 % of the total catalyst concentration. Other catalyst species that take part in the polymerization process have to be generated from this allyl pool into which they appear to relapse rather frequently.</dcterms:abstract>
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