Ruthenium(II) bipyridine complexes bearing quinoline–azoimine (NN′N″) tridentate ligands : Synthesis, spectral characterization, electrochemical properties and single-crystal X-ray structure analysis

Kurzanzeige
dc.contributor.authorAl-Noaimi, Mousa
dc.contributor.authorAbdel-Rahman, Obadah S.
dc.contributor.authorFasfous, Ismail I.
dc.contributor.authorEl-khateeb, Mohammad
dc.contributor.authorAwwadi, Firas A.
dc.contributor.authorWarad, Ismail
dc.date.accessioned2015-03-19T12:24:07Z
dc.date.available2015-03-19T12:24:07Z
dc.date.issued2014eng
dc.description.abstractFour octahedral ruthenium(II) azoimine–quinoline complexes having the general molecular formula [RuII(Lsingle bondY)(bpy)Cl](PF6) {Lsingle bondY = YC6H4Ndouble bond; length as m-dashNC(COCH3)double bond; length as m-dashNC9H6N, Y = H (1), CH3 (2), Br (3), NO2 (4) and bpy = 2,2′-bipyrdine} were synthesized. The azoimine–quinoline based ligands behave as NN′N″ tridentate donors and coordinated to ruthenium via azo-N′, imine-N′ and quinolone-N″ nitrogen atoms. The composition of the complexes has been established by elemental analysis, spectral methods (FT-IR, electronic, 1H NMR, UV/Vis and electrochemical (cyclic voltammetry) techniques. The crystal structure of complex 1 is reported. The Ru(II) oxidation state is greatly stabilized by the novel tridentate ligands, showing Ru(III/II) couples ranging from 0.93–1.27 V vs. Cp2Fe/Cp2Fe+. The absorption spectrum of 1 in dichloromethane was modeled by time-dependent density functional theory (TD-DFT).eng
dc.description.versionpublished
dc.identifier.doi10.1016/j.saa.2014.01.075eng
dc.identifier.urihttp://kops.uni-konstanz.de/handle/123456789/30426
dc.language.isoengeng
dc.subject.ddc540eng
dc.titleRuthenium(II) bipyridine complexes bearing quinoline–azoimine (NN′N″) tridentate ligands : Synthesis, spectral characterization, electrochemical properties and single-crystal X-ray structure analysiseng
dc.typeJOURNAL_ARTICLEeng
dspace.entity.typePublication
kops.citation.bibtex
@article{AlNoaimi2014Ruthe-30426,
  year={2014},
  doi={10.1016/j.saa.2014.01.075},
  title={Ruthenium(II) bipyridine complexes bearing quinoline–azoimine (NN′N″) tridentate ligands : Synthesis, spectral characterization, electrochemical properties and single-crystal X-ray structure analysis},
  volume={125},
  issn={1386-1425},
  journal={Spectrochimica Acta Part A : Molecular and Biomolecular Spectroscopy},
  pages={375--383},
  author={Al-Noaimi, Mousa and Abdel-Rahman, Obadah S. and Fasfous, Ismail I. and El-khateeb, Mohammad and Awwadi, Firas A. and Warad, Ismail}
}
kops.citation.iso690AL-NOAIMI, Mousa, Obadah S. ABDEL-RAHMAN, Ismail I. FASFOUS, Mohammad EL-KHATEEB, Firas A. AWWADI, Ismail WARAD, 2014. Ruthenium(II) bipyridine complexes bearing quinoline–azoimine (NN′N″) tridentate ligands : Synthesis, spectral characterization, electrochemical properties and single-crystal X-ray structure analysis. In: Spectrochimica Acta Part A : Molecular and Biomolecular Spectroscopy. 2014, 125, pp. 375-383. ISSN 1386-1425. eISSN 1873-3557. Available under: doi: 10.1016/j.saa.2014.01.075deu
kops.citation.iso690AL-NOAIMI, Mousa, Obadah S. ABDEL-RAHMAN, Ismail I. FASFOUS, Mohammad EL-KHATEEB, Firas A. AWWADI, Ismail WARAD, 2014. Ruthenium(II) bipyridine complexes bearing quinoline–azoimine (NN′N″) tridentate ligands : Synthesis, spectral characterization, electrochemical properties and single-crystal X-ray structure analysis. In: Spectrochimica Acta Part A : Molecular and Biomolecular Spectroscopy. 2014, 125, pp. 375-383. ISSN 1386-1425. eISSN 1873-3557. Available under: doi: 10.1016/j.saa.2014.01.075eng
kops.citation.rdf
<rdf:RDF
    xmlns:dcterms="http://purl.org/dc/terms/"
    xmlns:dc="http://purl.org/dc/elements/1.1/"
    xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#"
    xmlns:bibo="http://purl.org/ontology/bibo/"
    xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#"
    xmlns:foaf="http://xmlns.com/foaf/0.1/"
    xmlns:void="http://rdfs.org/ns/void#"
    xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > 
  <rdf:Description rdf:about="https://kops.uni-konstanz.de/server/rdf/resource/123456789/30426">
    <dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/>
    <dc:creator>El-khateeb, Mohammad</dc:creator>
    <dc:contributor>Warad, Ismail</dc:contributor>
    <void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/>
    <dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/>
    <dcterms:abstract xml:lang="eng">Four octahedral ruthenium(II) azoimine–quinoline complexes having the general molecular formula [RuII(Lsingle bondY)(bpy)Cl](PF&lt;sub&gt;6&lt;/sub&gt;) {Lsingle bondY = YC&lt;sub&gt;6&lt;/sub&gt;H&lt;sub&gt;4&lt;/sub&gt;Ndouble bond; length as m-dashNC(COCH&lt;sub&gt;3&lt;/sub&gt;)double bond; length as m-dashNC&lt;sub&gt;9&lt;/sub&gt;H&lt;sub&gt;6&lt;/sub&gt;N, Y = H (1), CH&lt;sub&gt;3&lt;/sub&gt; (2), Br (3), NO&lt;sub&gt;2&lt;/sub&gt; (4) and bpy = 2,2′-bipyrdine} were synthesized. The azoimine–quinoline based ligands behave as NN′N″ tridentate donors and coordinated to ruthenium via azo-N′, imine-N′ and quinolone-N″ nitrogen atoms. The composition of the complexes has been established by elemental analysis, spectral methods (FT-IR, electronic, &lt;sup&gt;1&lt;/sup&gt;H NMR, UV/Vis and electrochemical (cyclic voltammetry) techniques. The crystal structure of complex 1 is reported. The Ru(II) oxidation state is greatly stabilized by the novel tridentate ligands, showing Ru(III/II) couples ranging from 0.93–1.27 V vs. Cp&lt;sub&gt;2&lt;/sub&gt;Fe/Cp&lt;sub&gt;2&lt;/sub&gt;Fe&lt;sup&gt;+&lt;/sup&gt;. The absorption spectrum of 1 in dichloromethane was modeled by time-dependent density functional theory (TD-DFT).</dcterms:abstract>
    <dcterms:issued>2014</dcterms:issued>
    <dc:contributor>Al-Noaimi, Mousa</dc:contributor>
    <dc:creator>Fasfous, Ismail I.</dc:creator>
    <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/30426"/>
    <dc:creator>Abdel-Rahman, Obadah S.</dc:creator>
    <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2015-03-19T12:24:07Z</dc:date>
    <dc:creator>Warad, Ismail</dc:creator>
    <dc:language>eng</dc:language>
    <foaf:homepage rdf:resource="http://localhost:8080/"/>
    <dc:creator>Awwadi, Firas A.</dc:creator>
    <dc:contributor>Awwadi, Firas A.</dc:contributor>
    <dc:contributor>El-khateeb, Mohammad</dc:contributor>
    <dc:contributor>Abdel-Rahman, Obadah S.</dc:contributor>
    <dc:creator>Al-Noaimi, Mousa</dc:creator>
    <dcterms:title>Ruthenium(II) bipyridine complexes bearing quinoline–azoimine (NN′N″) tridentate ligands : Synthesis, spectral characterization, electrochemical properties and single-crystal X-ray structure analysis</dcterms:title>
    <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2015-03-19T12:24:07Z</dcterms:available>
    <dc:contributor>Fasfous, Ismail I.</dc:contributor>
  </rdf:Description>
</rdf:RDF>
kops.sourcefieldSpectrochimica Acta Part A : Molecular and Biomolecular Spectroscopy. 2014, <b>125</b>, pp. 375-383. ISSN 1386-1425. eISSN 1873-3557. Available under: doi: 10.1016/j.saa.2014.01.075deu
kops.sourcefield.plainSpectrochimica Acta Part A : Molecular and Biomolecular Spectroscopy. 2014, 125, pp. 375-383. ISSN 1386-1425. eISSN 1873-3557. Available under: doi: 10.1016/j.saa.2014.01.075deu
kops.sourcefield.plainSpectrochimica Acta Part A : Molecular and Biomolecular Spectroscopy. 2014, 125, pp. 375-383. ISSN 1386-1425. eISSN 1873-3557. Available under: doi: 10.1016/j.saa.2014.01.075eng
relation.isAuthorOfPublication30840f8b-2ee2-4b88-b33a-adbeb9d0e77d
relation.isAuthorOfPublication.latestForDiscovery30840f8b-2ee2-4b88-b33a-adbeb9d0e77d
source.bibliographicInfo.fromPage375eng
source.bibliographicInfo.toPage383eng
source.bibliographicInfo.volume125eng
source.identifier.eissn1873-3557eng
source.identifier.issn1386-1425eng
source.periodicalTitleSpectrochimica Acta Part A : Molecular and Biomolecular Spectroscopyeng
temp.internal.duplicates<p>Keine Dubletten gefunden. Letzte Überprüfung: 30.01.2015 10:23:47</p>deu

Dateien

Sammlungen

Chemie: Publikationen