Publikation: Chemical vapour infiltration of pyrolytic carbon : an electron spin resonance analysis
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2004
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Synthetic Metals. 2004, 142(1-3), pp. 13-19. ISSN 0379-6779. eISSN 1879-3290. Available under: doi: 10.1016/S0379-6779(03)00415-6
Zusammenfassung
A carbon fibre felt with a fibre volume fraction of 7% was densified by chemical vapour infiltration of pyrolytic carbon from methane at about 1100 °C using an isothermal, isobaric process. Specimens of 1 mm3 size were cut out and analysed by electron spin resonance (ESR) in as-infiltrated form and after annealing at 2200 or 2900 °C. The temperature and orientation dependence of ESR line shape, width, intensity, and g-tensor are derived. Preferred orientation and degree of graphitisation of the deposited pyrolytic carbon are discussed.
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Fachgebiet (DDC)
540 Chemie
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Chemical vapour infiltration; Electron spin resonance
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DRESCHER, Malte, Moez GUELLALI, Klaus J. HÜTTINGER, Elmar DORMANN, 2004. Chemical vapour infiltration of pyrolytic carbon : an electron spin resonance analysis. In: Synthetic Metals. 2004, 142(1-3), pp. 13-19. ISSN 0379-6779. eISSN 1879-3290. Available under: doi: 10.1016/S0379-6779(03)00415-6BibTex
@article{Drescher2004-04Chemi-40091,
year={2004},
doi={10.1016/S0379-6779(03)00415-6},
title={Chemical vapour infiltration of pyrolytic carbon : an electron spin resonance analysis},
number={1-3},
volume={142},
issn={0379-6779},
journal={Synthetic Metals},
pages={13--19},
author={Drescher, Malte and Guellali, Moez and Hüttinger, Klaus J. and Dormann, Elmar}
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<dcterms:abstract xml:lang="eng">A carbon fibre felt with a fibre volume fraction of 7% was densified by chemical vapour infiltration of pyrolytic carbon from methane at about 1100 °C using an isothermal, isobaric process. Specimens of 1 mm<sup>3</sup> size were cut out and analysed by electron spin resonance (ESR) in as-infiltrated form and after annealing at 2200 or 2900 °C. The temperature and orientation dependence of ESR line shape, width, intensity, and g-tensor are derived. Preferred orientation and degree of graphitisation of the deposited pyrolytic carbon are discussed.</dcterms:abstract>
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