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Enhancement of magnetic field effect in Ru(bpy)3 2+ / MV 2+ system by Ru(bpy)3 2+ -Ag+ exciplex formation

Enhancement of magnetic field effect in Ru(bpy)3 2+ / MV 2+ system by Ru(bpy)3 2+ -Ag+ exciplex formation

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FODOR, Lajos, Attila HORVÁTH, Karsten A. HÖTZER, Stefan WALBERT, Ulrich STEINER, 2000. Enhancement of magnetic field effect in Ru(bpy)3 2+ / MV 2+ system by Ru(bpy)3 2+ -Ag+ exciplex formation. In: Chemical Physics Letters. 316(5-6), pp. 411-418. ISSN 0009-2614

@article{Fodor2000Enhan-9952, title={Enhancement of magnetic field effect in Ru(bpy)3 2+ / MV 2+ system by Ru(bpy)3 2+ -Ag+ exciplex formation}, year={2000}, doi={10.1016/S0009-2614(99)01307-X}, number={5-6}, volume={316}, issn={0009-2614}, journal={Chemical Physics Letters}, pages={411--418}, author={Fodor, Lajos and Horváth, Attila and Hötzer, Karsten A. and Walbert, Stefan and Steiner, Ulrich} }

<rdf:RDF xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns:bibo="http://purl.org/ontology/bibo/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:dcterms="http://purl.org/dc/terms/" xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > <rdf:Description rdf:about="https://kops.uni-konstanz.de/rdf/resource/123456789/9952"> <dc:creator>Walbert, Stefan</dc:creator> <dc:contributor>Walbert, Stefan</dc:contributor> <dcterms:abstract xml:lang="eng">The influence of ionic strength variation and of exciplex formation between silver ions and triplet excited RuL32+ (L=bipyridine, phenanthroline) on the photo electron transfer kinetics of the complex with methylviologen and the magnetic field dependence of free radical formation efficiency has been studied by laser flash spectroscopy. The magnetic field effect consisting in a decrease of the efficiency of cage escape ηce in the Ru(bpy)32+/MV2+ system is enhanced by 40% when exciplex formation between Ag+ ions and triplet excited RuL32+ complexes takes place. The relevant kinetic parameters have been determined by magnetokinetic model calculations.</dcterms:abstract> <dcterms:issued>2000</dcterms:issued> <dc:creator>Hötzer, Karsten A.</dc:creator> <dc:contributor>Hötzer, Karsten A.</dc:contributor> <dc:contributor>Horváth, Attila</dc:contributor> <dcterms:title>Enhancement of magnetic field effect in Ru(bpy)3 2+ / MV 2+ system by Ru(bpy)3 2+ -Ag+ exciplex formation</dcterms:title> <dc:creator>Steiner, Ulrich</dc:creator> <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T18:15:32Z</dcterms:available> <dc:rights>deposit-license</dc:rights> <dc:creator>Fodor, Lajos</dc:creator> <dcterms:rights rdf:resource="https://creativecommons.org/licenses/by-nc-nd/2.0/legalcode"/> <dc:contributor>Fodor, Lajos</dc:contributor> <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T18:15:32Z</dc:date> <dc:contributor>Steiner, Ulrich</dc:contributor> <dc:language>eng</dc:language> <dc:creator>Horváth, Attila</dc:creator> <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/9952"/> <dc:format>application/pdf</dc:format> <dcterms:bibliographicCitation>First publ. in: Chemical Physics Letters 316 (2000), pp. 411-418</dcterms:bibliographicCitation> </rdf:Description> </rdf:RDF>

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