KOPS - Das Institutionelle Repositorium der Universität Konstanz

Interference of heavy-atom with magnetic spin effects in spin-correlated micellar radical pairs

Interference of heavy-atom with magnetic spin effects in spin-correlated micellar radical pairs

Zitieren

Dateien zu dieser Ressource

Prüfsumme: MD5:797c35e79b7c910b51fcf18c3804ffea

WU, Jie Qiang, Dietrich BAUMANN, Ulrich STEINER, 1995. Interference of heavy-atom with magnetic spin effects in spin-correlated micellar radical pairs. In: Molecular Physics. 84(5), pp. 981-994. ISSN 0026-8976. eISSN 1362-3028

@article{Wu1995Inter-9939, title={Interference of heavy-atom with magnetic spin effects in spin-correlated micellar radical pairs}, year={1995}, doi={10.1080/00268979500100681}, number={5}, volume={84}, issn={0026-8976}, journal={Molecular Physics}, pages={981--994}, author={Wu, Jie Qiang and Baumann, Dietrich and Steiner, Ulrich} }

<rdf:RDF xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns:bibo="http://purl.org/ontology/bibo/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:dcterms="http://purl.org/dc/terms/" xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > <rdf:Description rdf:about="https://kops.uni-konstanz.de/rdf/resource/123456789/9939"> <dcterms:title>Interference of heavy-atom with magnetic spin effects in spin-correlated micellar radical pairs</dcterms:title> <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T18:15:27Z</dc:date> <dcterms:issued>1995</dcterms:issued> <dcterms:abstract xml:lang="eng">The recombination kinetics of the radical pairs 3(SeH· .. An·+), with SeH+ = selenine, An = aniline, and 3(TH· .. An·+) with TH+ = thionine, p-Cl-An = 4-chloroaniline, in benzene/cetyldimethylbenzylammonium chloride/H2O reverse microemulsions was measured by ns-laser flash photolysis as a function of magnetic field and nanodroplet size. By comparison with the behaviour of the 3(TH· .. An·+) radical pairs evidence was provided that, besides the main route of triplet radical pair recombination through triplet to singlet spin conversion in situations when the radicals are separate and subsequent reaction on re-encountering as singlet radical pair, there is a finite probability that radical pairs encountering with overall triplet spin will directly recombine through electron transfer to singlet ground state products. The probability of this process, which is induced by spin-orbit coupling and is independent of a magnetic field, was evaluated for the three radical pairs specified above.</dcterms:abstract> <dc:rights>deposit-license</dc:rights> <dcterms:bibliographicCitation>First publ. in: Molecular Physics 84 (1995), 5, pp. 981-994</dcterms:bibliographicCitation> <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T18:15:27Z</dcterms:available> <dc:creator>Wu, Jie Qiang</dc:creator> <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/9939"/> <dcterms:rights rdf:resource="https://creativecommons.org/licenses/by-nc-nd/2.0/legalcode"/> <dc:creator>Baumann, Dietrich</dc:creator> <dc:contributor>Wu, Jie Qiang</dc:contributor> <dc:language>eng</dc:language> <dc:contributor>Steiner, Ulrich</dc:contributor> <dc:contributor>Baumann, Dietrich</dc:contributor> <dc:format>application/pdf</dc:format> <dc:creator>Steiner, Ulrich</dc:creator> </rdf:Description> </rdf:RDF>

Dateiabrufe seit 01.10.2014 (Informationen über die Zugriffsstatistik)

Steiner_1995_Interference.pdf 145

Das Dokument erscheint in:

deposit-license Solange nicht anders angezeigt, wird die Lizenz wie folgt beschrieben: deposit-license

KOPS Suche


Stöbern

Mein Benutzerkonto