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Multinuclear NMR studies and reaction with tert-Butyl Isocyanide of Dinuclear Tungsten- or Molybdenum-Palladium Micro-Alkylidene Complexes. X-ray structure of [PdI{Micro-C(p-tolyl)dmba}{Micro-CO}Mo(Cp)(CN-t-Bu)2]

Multinuclear NMR studies and reaction with tert-Butyl Isocyanide of Dinuclear Tungsten- or Molybdenum-Palladium Micro-Alkylidene Complexes. X-ray structure of [PdI{Micro-C(p-tolyl)dmba}{Micro-CO}Mo(Cp)(CN-t-Bu)2]

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MACCHIONI, Alceo, Paul S. PREGOSIN, Philippus F. ENGEL, Stefan MECKING, Michel PFEFFER, Jean-Claude DARAN, Jacqueline VAISSERMANN, 1995. Multinuclear NMR studies and reaction with tert-Butyl Isocyanide of Dinuclear Tungsten- or Molybdenum-Palladium Micro-Alkylidene Complexes. X-ray structure of [PdI{Micro-C(p-tolyl)dmba}{Micro-CO}Mo(Cp)(CN-t-Bu)2]. In: Organometallics. 14(4), pp. 1637-1645. ISSN 0276-7333. eISSN 1520-6041

@article{Macchioni1995Multi-9907, title={Multinuclear NMR studies and reaction with tert-Butyl Isocyanide of Dinuclear Tungsten- or Molybdenum-Palladium Micro-Alkylidene Complexes. X-ray structure of [PdI{Micro-C(p-tolyl)dmba}{Micro-CO}Mo(Cp)(CN-t-Bu)2]}, year={1995}, number={4}, volume={14}, issn={0276-7333}, journal={Organometallics}, pages={1637--1645}, author={Macchioni, Alceo and Pregosin, Paul S. and Engel, Philippus F. and Mecking, Stefan and Pfeffer, Michel and Daran, Jean-Claude and Vaissermann, Jacqueline} }

<rdf:RDF xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns:bibo="http://purl.org/ontology/bibo/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:dcterms="http://purl.org/dc/terms/" xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > <rdf:Description rdf:about="https://kops.uni-konstanz.de/rdf/resource/123456789/9907"> <dc:language>eng</dc:language> <dc:creator>Engel, Philippus F.</dc:creator> <dc:creator>Daran, Jean-Claude</dc:creator> <dc:creator>Pfeffer, Michel</dc:creator> <dcterms:title>Multinuclear NMR studies and reaction with tert-Butyl Isocyanide of Dinuclear Tungsten- or Molybdenum-Palladium Micro-Alkylidene Complexes. X-ray structure of [PdI{Micro-C(p-tolyl)dmba}{Micro-CO}Mo(Cp)(CN-t-Bu)2]</dcterms:title> <dc:contributor>Pfeffer, Michel</dc:contributor> <dcterms:abstract xml:lang="deu">The lH, 13C, and 183W NMR characteristics for a series of dinuclear complexes containing a W-(Micro-CR1R2)-Pd moiety are reported. These compounds, derived from the reaction of the carbyne complex (Cp)(C0)2M(=CR), M = Mo, W, R = cyclopentenyl or p-tolyl, with a dinuclear cyclopalladated complex are shown to possess an y2-bond from the cyclopentenyl or p-tolyl fragment to the metal, thus attaining an 18-electron configuration at M. The bridging carbon has its 13C absorption at delta = 142.4-155.1. Reaction of a Mo derivative with 2 equiv of t-BuNC displaces the y2-bond and affords a new complex, [PdI{Micro-C(p-tolyl)-dmba){Micro-CO)Mo(Cp)(t-BuNC)2], whose structure in the solid state was determined by X-ray diffraction. The solution NMR data for this complex clearly show that the y2-bond is no longer present.</dcterms:abstract> <dc:format>application/pdf</dc:format> <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T18:15:14Z</dc:date> <dc:contributor>Vaissermann, Jacqueline</dc:contributor> <dc:contributor>Pregosin, Paul S.</dc:contributor> <dc:contributor>Engel, Philippus F.</dc:contributor> <dc:contributor>Mecking, Stefan</dc:contributor> <dc:creator>Mecking, Stefan</dc:creator> <dc:rights>deposit-license</dc:rights> <dc:contributor>Daran, Jean-Claude</dc:contributor> <dc:creator>Vaissermann, Jacqueline</dc:creator> <dcterms:issued>1995</dcterms:issued> <dcterms:rights rdf:resource="https://creativecommons.org/licenses/by-nc-nd/2.0/legalcode"/> <dcterms:bibliographicCitation>First publ. in: Organometallics ; 14 (1995), 4. - S. 1637-1645</dcterms:bibliographicCitation> <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/9907"/> <dc:contributor>Macchioni, Alceo</dc:contributor> <dc:creator>Pregosin, Paul S.</dc:creator> <dc:creator>Macchioni, Alceo</dc:creator> </rdf:Description> </rdf:RDF>

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