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Zinc(II)-Chloride Induced Thioalkylation of Aluminium Enolates : Enantioselective Synthesis of Estradiol-3-Methyl-17-tert-Butyl Diether

Zinc(II)-Chloride Induced Thioalkylation of Aluminium Enolates : Enantioselective Synthesis of Estradiol-3-Methyl-17-tert-Butyl Diether

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GROTH, Ulrich, Thomas KOHLER, Thomas TAAPKEN, 1991. Zinc(II)-Chloride Induced Thioalkylation of Aluminium Enolates : Enantioselective Synthesis of Estradiol-3-Methyl-17-tert-Butyl Diether. In: Tetrahedron. 47(36), pp. 7583-7592. ISSN 0040-4020

@article{Groth1991Zinc(-9885, title={Zinc(II)-Chloride Induced Thioalkylation of Aluminium Enolates : Enantioselective Synthesis of Estradiol-3-Methyl-17-tert-Butyl Diether}, year={1991}, doi={10.1016/S0040-4020(01)88282-X}, number={36}, volume={47}, issn={0040-4020}, journal={Tetrahedron}, pages={7583--7592}, author={Groth, Ulrich and Kohler, Thomas and Taapken, Thomas} }

<rdf:RDF xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns:bibo="http://purl.org/ontology/bibo/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:dcterms="http://purl.org/dc/terms/" xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > <rdf:Description rdf:about="https://kops.uni-konstanz.de/rdf/resource/123456789/9885"> <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/9885"/> <dc:language>eng</dc:language> <dc:creator>Kohler, Thomas</dc:creator> <dcterms:issued>1991</dcterms:issued> <dc:rights>deposit-license</dc:rights> <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T18:15:05Z</dc:date> <dc:creator>Taapken, Thomas</dc:creator> <dc:contributor>Taapken, Thomas</dc:contributor> <dcterms:abstract xml:lang="eng">Zinc(II)-chloride induced thioalkylation of the aluminium enolate 6 generated by conlugate reduction of the enone 5 leads - directly or via its trimethylsilylenol ether 6 - to alkylated hydrindanones 10 which are important intermediates in the synthesis of 19-norsteroids such as the title compound estradiol-3-methyl-17-tert-butyl diether 12</dcterms:abstract> <dcterms:title>Zinc(II)-Chloride Induced Thioalkylation of Aluminium Enolates : Enantioselective Synthesis of Estradiol-3-Methyl-17-tert-Butyl Diether</dcterms:title> <dc:format>application/pdf</dc:format> <dcterms:bibliographicCitation>First publ. in: Tetrahedron 47 (1991), 36, pp. 7583-7592</dcterms:bibliographicCitation> <dc:contributor>Groth, Ulrich</dc:contributor> <dcterms:rights rdf:resource="https://creativecommons.org/licenses/by-nc-nd/2.0/legalcode"/> <dc:contributor>Kohler, Thomas</dc:contributor> <dc:creator>Groth, Ulrich</dc:creator> <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T18:15:05Z</dcterms:available> </rdf:Description> </rdf:RDF>

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