KOPS - Das Institutionelle Repositorium der Universität Konstanz

Spin Chemistry of Ru(II)-Trisdiimine Complex Photooxidation in Magnetic Fields up to 17.5 Tesla

Spin Chemistry of Ru(II)-Trisdiimine Complex Photooxidation in Magnetic Fields up to 17.5 Tesla

Zitieren

Dateien zu dieser Ressource

Prüfsumme: MD5:c253dd3a8acb258e94063efb3f8622d8

BÜRSSNER, Dieter, Ulrich STEINER, 1994. Spin Chemistry of Ru(II)-Trisdiimine Complex Photooxidation in Magnetic Fields up to 17.5 Tesla. In: Coordination Chemistry Reviews. 132, pp. 51-56. ISSN 0010-8545

@article{Burner1994Chemi-9860, title={Spin Chemistry of Ru(II)-Trisdiimine Complex Photooxidation in Magnetic Fields up to 17.5 Tesla}, year={1994}, doi={10.1016/0010-8545(94)80023-5}, volume={132}, issn={0010-8545}, journal={Coordination Chemistry Reviews}, pages={51--56}, author={Bürßner, Dieter and Steiner, Ulrich} }

<rdf:RDF xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns:bibo="http://purl.org/ontology/bibo/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:dcterms="http://purl.org/dc/terms/" xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > <rdf:Description rdf:about="https://kops.uni-konstanz.de/rdf/resource/123456789/9860"> <dcterms:abstract xml:lang="eng">The magnetic field dependence of the efficiency of cage escape ηce, which is due to the magnetic field and spin control of the effective rate of electron backtransfer in geminate pairs of photogenerated Ru(III) complexes and electron acceptor radicals, has been measured for Ru(bpy)2+/3 and Ru(phen)2+/3 over the entire field range from 0 to 17.5 T. These magnetic field dependent data on ηce, together with the experimental values of the g-tensor components of the Ru(III) complex, allow us to evaluate unambiguously and without recourse to supplementary information, the absolute values of the rate constants of cage escape (kce ), (spin-conserving) backward electron transfer (kbet) and electron spin relaxation time τ5 of the Ru(III) complex.</dcterms:abstract> <dc:language>eng</dc:language> <dc:format>application/pdf</dc:format> <dcterms:issued>1994</dcterms:issued> <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/9860"/> <dc:contributor>Steiner, Ulrich</dc:contributor> <dcterms:rights rdf:resource="https://creativecommons.org/licenses/by-nc-nd/2.0/legalcode"/> <dc:creator>Steiner, Ulrich</dc:creator> <dc:rights>deposit-license</dc:rights> <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T18:14:55Z</dc:date> <dc:creator>Bürßner, Dieter</dc:creator> <dcterms:bibliographicCitation>First publ. in: Coordination Chemistry Reviews 132 (1994), pp. 51-56</dcterms:bibliographicCitation> <dcterms:title>Spin Chemistry of Ru(II)-Trisdiimine Complex Photooxidation in Magnetic Fields up to 17.5 Tesla</dcterms:title> <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T18:14:55Z</dcterms:available> <dc:contributor>Bürßner, Dieter</dc:contributor> </rdf:Description> </rdf:RDF>

Dateiabrufe seit 01.10.2014 (Informationen über die Zugriffsstatistik)

Steiner_1994_Spin.pdf 65

Das Dokument erscheint in:

deposit-license Solange nicht anders angezeigt, wird die Lizenz wie folgt beschrieben: deposit-license

KOPS Suche


Stöbern

Mein Benutzerkonto