@article{Eckenberg1994Addit-9844,
  year={1994},
  doi={10.1002/jlac.199419940707},
  title={Addition of Cerium Reagents Derived from (Trimethylsilyl)propargyl Bromide to Aldehydes},
  number={7},
  volume={1994},
  issn={0170-2041},
  journal={Liebigs Annalen der Chemie},
  pages={673--677},
  author={Eckenberg, Peter and Groth, Ulrich and Köhler, Thomas}
}

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    <dc:contributor>Groth, Ulrich</dc:contributor>
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    <dc:contributor>Eckenberg, Peter</dc:contributor>
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    <dc:contributor>Köhler, Thomas</dc:contributor>
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    <dcterms:title>Addition of Cerium Reagents Derived from (Trimethylsilyl)propargyl Bromide to Aldehydes</dcterms:title>
    <dcterms:abstract xml:lang="deu">The addition of (trimethylsilyl)propargylmagnesium bromide (9) to aldehydes afforded predominantly the allenylic alcohols rac-10. The regioselectivity of this addition changes dramatically when organocerium reagents were used for the addition. In this case nearly exclusive formation of the homopropargylic alcohols rac-8 was observed. Highest selectivity for this process was obtained when cerium(III) isopropoxide (13) was used as a precursor for the formation of the organocerium reagent.</dcterms:abstract>
    <dcterms:bibliographicCitation>First publ. in: Liebigs Annalen der Chemie 1994, 7, pp. 673-677</dcterms:bibliographicCitation>
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    <dc:creator>Köhler, Thomas</dc:creator>
    <dc:rights>Attribution-NonCommercial-NoDerivs 2.0 Generic</dc:rights>
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