Fabrication of EuF3-Mesocrystals in a Gel Matrix

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LAUSSER, Christine, Michael U. KUMKE, Markus ANTONIETTI, Helmut CÖLFEN, 2010. Fabrication of EuF3-Mesocrystals in a Gel Matrix. In: Zeitschrift für anorganische und allgemeine Chemie. 636(11), pp. 1925-1930. eISSN 0044-2313

@article{Lausser2010Fabri-9826, title={Fabrication of EuF3-Mesocrystals in a Gel Matrix}, year={2010}, doi={10.1002/zaac.201000098}, number={11}, volume={636}, journal={Zeitschrift für anorganische und allgemeine Chemie}, pages={1925--1930}, author={Lausser, Christine and Kumke, Michael U. and Antonietti, Markus and Cölfen, Helmut} }

<rdf:RDF xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns:bibo="http://purl.org/ontology/bibo/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:dcterms="http://purl.org/dc/terms/" xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > <rdf:Description rdf:about="https://kops.uni-konstanz.de/rdf/resource/123456789/9826"> <dc:contributor>Kumke, Michael U.</dc:contributor> <dc:contributor>Lausser, Christine</dc:contributor> <dcterms:rights rdf:resource="http://nbn-resolving.org/urn:nbn:de:bsz:352-20140905103416863-3868037-7"/> <dcterms:abstract xml:lang="eng">Europium(III) fluoride mesocrystals were synthesised in an organic matrix. This matrix is a gel formed by Eu3+ ions and a polycarboxylate/sulfonate copolymer, ACUSOL 588G. In the gel phase, the local amount of europium ions is very high since Eu3+ acts as a crosslinker, and crystallisation occurs upon addition of F . Nucleated seed crystals in the gel phase grow by further ion attachment and form mesocrystals by mutual orientation of the EuF3 particles in the gel. We propose a dipole field as reason for this alignment and that the dipolar character of the particles originates from adsorption of the polyelectrolyte on charged crystal faces.</dcterms:abstract> <dc:creator>Lausser, Christine</dc:creator> <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/9826"/> <dcterms:issued>2010</dcterms:issued> <dc:format>application/pdf</dc:format> <dcterms:title>Fabrication of EuF3-Mesocrystals in a Gel Matrix</dcterms:title> <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T18:14:41Z</dc:date> <dc:contributor>Antonietti, Markus</dc:contributor> <dc:contributor>Cölfen, Helmut</dc:contributor> <dcterms:bibliographicCitation>First publ. in: Zeitschrift für anorganische und allgemeine Chemie 636 (2010), 11, pp. 1925-1930</dcterms:bibliographicCitation> <dc:language>eng</dc:language> <dc:creator>Kumke, Michael U.</dc:creator> <dc:creator>Antonietti, Markus</dc:creator> <dc:creator>Cölfen, Helmut</dc:creator> <dc:rights>deposit-license</dc:rights> <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T18:14:41Z</dcterms:available> </rdf:Description> </rdf:RDF>

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