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Ethylene polymerization in supercritical carbon dioxide with binuclear nickel(II) catalysts

Ethylene polymerization in supercritical carbon dioxide with binuclear nickel(II) catalysts

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Prüfsumme: MD5:298276023f637e2c2229d1fd30a0be90

GUIRONNET, Damien, Tobias FRIEDBERGER, Stefan MECKING, 2009. Ethylene polymerization in supercritical carbon dioxide with binuclear nickel(II) catalysts. In: Dalton Transactions(41), pp. 8929-8934. ISSN 1477-9226. eISSN 1477-9234

@article{Guironnet2009Ethyl-9789, title={Ethylene polymerization in supercritical carbon dioxide with binuclear nickel(II) catalysts}, year={2009}, doi={10.1039/b912883b}, number={41}, issn={1477-9226}, journal={Dalton Transactions}, pages={8929--8934}, author={Guironnet, Damien and Friedberger, Tobias and Mecking, Stefan} }

<rdf:RDF xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns:bibo="http://purl.org/ontology/bibo/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:dcterms="http://purl.org/dc/terms/" xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > <rdf:Description rdf:about="https://kops.uni-konstanz.de/rdf/resource/123456789/9789"> <dcterms:issued>2009</dcterms:issued> <dc:creator>Mecking, Stefan</dc:creator> <dc:language>eng</dc:language> <dc:contributor>Guironnet, Damien</dc:contributor> <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T18:14:25Z</dcterms:available> <dc:rights>deposit-license</dc:rights> <dc:contributor>Friedberger, Tobias</dc:contributor> <dc:creator>Friedberger, Tobias</dc:creator> <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/9789"/> <dc:format>application/pdf</dc:format> <dc:creator>Guironnet, Damien</dc:creator> <dcterms:bibliographicCitation>First publ. in: Dalton Transactions 2009, 41, pp. 8929-8934</dcterms:bibliographicCitation> <dcterms:abstract>A series of new, highly fluorinated neutral (kappa(2)-N,O) chelated Ni(II) binuclear complexes based on salicylaldimines bridged in p-position of the N-aryl group were prepared. The complexes are single-component catalyst precursors for ethylene polymerization in supercritical carbon dioxide and toluene. Solubility of the catalyst precursors in supercritical carbon dioxide is effected by a large number of up to 18 trifluoromethyl groups per molecule. Semicrystalline polyethylene with a low degree of branching is formed (ca. 10 branches/1000 carbon atoms). Polymer microstructures are independent of the nature of the bridging moiety, while stability of the catalysts appears to differ.</dcterms:abstract> <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T18:14:25Z</dc:date> <dcterms:rights rdf:resource="http://nbn-resolving.org/urn:nbn:de:bsz:352-20140905103416863-3868037-7"/> <dcterms:title>Ethylene polymerization in supercritical carbon dioxide with binuclear nickel(II) catalysts</dcterms:title> <dc:contributor>Mecking, Stefan</dc:contributor> </rdf:Description> </rdf:RDF>

Dateiabrufe seit 01.10.2014 (Informationen über die Zugriffsstatistik)

Mecking_2009_Metal_catalysed_Polymerisation_DALTON.pdf 158

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