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Spin dynamics and zero-field splitting constants of the triplet exciplex generated by photoinduced electron transfer reaction between erythrosin B and duroquinone

Spin dynamics and zero-field splitting constants of the triplet exciplex generated by photoinduced electron transfer reaction between erythrosin B and duroquinone

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TACHIKAWA, Takashi, Yasuhiro KOBORI, Kimio AKIYAMA, Akio KATSUKI, Ulrich STEINER, Shozo TERO-KUBOTA, 2002. Spin dynamics and zero-field splitting constants of the triplet exciplex generated by photoinduced electron transfer reaction between erythrosin B and duroquinone. In: Chemical physics letters. 360(1/2), pp. 12-21. ISSN 0009-2614. Available under: doi: 10.1016/S0009-2614(02)00804-7

@article{Tachikawa2002dynam-9785, title={Spin dynamics and zero-field splitting constants of the triplet exciplex generated by photoinduced electron transfer reaction between erythrosin B and duroquinone}, year={2002}, doi={10.1016/S0009-2614(02)00804-7}, number={1/2}, volume={360}, issn={0009-2614}, journal={Chemical physics letters}, pages={12--21}, author={Tachikawa, Takashi and Kobori, Yasuhiro and Akiyama, Kimio and Katsuki, Akio and Steiner, Ulrich and Tero-Kubota, Shozo} }

<rdf:RDF xmlns:dcterms="http://purl.org/dc/terms/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns:bibo="http://purl.org/ontology/bibo/" xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#" xmlns:foaf="http://xmlns.com/foaf/0.1/" xmlns:void="http://rdfs.org/ns/void#" xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > <rdf:Description rdf:about="https://kops.uni-konstanz.de/rdf/resource/123456789/9785"> <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T18:14:24Z</dc:date> <dcterms:rights rdf:resource="https://creativecommons.org/licenses/by-nc-nd/2.0/legalcode"/> <dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/rdf/resource/123456789/29"/> <dcterms:title>Spin dynamics and zero-field splitting constants of the triplet exciplex generated by photoinduced electron transfer reaction between erythrosin B and duroquinone</dcterms:title> <dc:contributor>Steiner, Ulrich</dc:contributor> <dc:creator>Katsuki, Akio</dc:creator> <dc:contributor>Tachikawa, Takashi</dc:contributor> <dc:contributor>Tero-Kubota, Shozo</dc:contributor> <dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/rdf/resource/123456789/29"/> <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/9785"/> <dcterms:bibliographicCitation>First publ. in: Chemical physics letters 360 (2002), 1/2, pp. 12-21</dcterms:bibliographicCitation> <dc:creator>Akiyama, Kimio</dc:creator> <void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/> <dc:language>eng</dc:language> <dc:contributor>Kobori, Yasuhiro</dc:contributor> <foaf:homepage rdf:resource="http://localhost:8080/jspui"/> <dc:creator>Tachikawa, Takashi</dc:creator> <dc:contributor>Akiyama, Kimio</dc:contributor> <dc:rights>terms-of-use</dc:rights> <dspace:hasBitstream rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/9785/1/Nr80.pdf"/> <dcterms:issued>2002</dcterms:issued> <dcterms:hasPart rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/9785/1/Nr80.pdf"/> <dc:creator>Tero-Kubota, Shozo</dc:creator> <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T18:14:24Z</dcterms:available> <dcterms:abstract xml:lang="eng">The spin dynamics of the duroquinone anion radical generated by photoinduced electron transfer reactions from triplet erythrosin B to duroquinone has been studied by using transient absorption and pulsed FT-EPR spectroscopy. Triplet exciplex formation as the reaction intermediate is verified by the observation of spin orbit coupling induced electron spin polarization. The kinetic parameters for exciplex formation and the intrinsic enhancement factors of electron spin polarization are determined in various alcoholic solvents. The zero-field splitting constants of the triplet exciplex are determined by the analysis of the solvent viscosity dependence of the enhancement factors of the electron spin polarization.</dcterms:abstract> <dc:creator>Steiner, Ulrich</dc:creator> <dc:contributor>Katsuki, Akio</dc:contributor> <dc:format>application/pdf</dc:format> <dc:creator>Kobori, Yasuhiro</dc:creator> </rdf:Description> </rdf:RDF>

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