Adiabatic rotation of effective spin (II) : spin-rotational relaxation


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SEREBRENNIKOV, Yuri A., Ulrich STEINER, 1994. Adiabatic rotation of effective spin (II) : spin-rotational relaxation. In: Journal of Chemical Physics. 100(10), pp. 7508-7514. ISSN 0021-9606. Available under: doi: 10.1063/1.466844

@article{Serebrennikov1994Adiab-9757, title={Adiabatic rotation of effective spin (II) : spin-rotational relaxation}, year={1994}, doi={10.1063/1.466844}, number={10}, volume={100}, issn={0021-9606}, journal={Journal of Chemical Physics}, pages={7508--7514}, author={Serebrennikov, Yuri A. and Steiner, Ulrich} }

<rdf:RDF xmlns:dcterms="" xmlns:dc="" xmlns:rdf="" xmlns:bibo="" xmlns:dspace="" xmlns:foaf="" xmlns:void="" xmlns:xsd="" > <rdf:Description rdf:about=""> <dcterms:issued>1994</dcterms:issued> <dc:creator>Serebrennikov, Yuri A.</dc:creator> <dc:contributor>Steiner, Ulrich</dc:contributor> <dcterms:title>Adiabatic rotation of effective spin (II) : spin-rotational relaxation</dcterms:title> <dcterms:available rdf:datatype="">2011-03-24T18:14:12Z</dcterms:available> <dc:date rdf:datatype="">2011-03-24T18:14:12Z</dc:date> <foaf:homepage rdf:resource="http://localhost:8080/jspui"/> <dcterms:rights rdf:resource=""/> <dcterms:isPartOf rdf:resource=""/> <dspace:hasBitstream rdf:resource=""/> <dspace:isPartOfCollection rdf:resource=""/> <dc:rights>terms-of-use</dc:rights> <dc:creator>Steiner, Ulrich</dc:creator> <dcterms:hasPart rdf:resource=""/> <dc:contributor>Serebrennikov, Yuri A.</dc:contributor> <dcterms:bibliographicCitation>First publ. in: Journal of Chemical Physics 100 (1994), 10, pp. 7508-7514</dcterms:bibliographicCitation> <bibo:uri rdf:resource=""/> <dc:format>application/pdf</dc:format> <void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/> <dc:language>eng</dc:language> <dcterms:abstract xml:lang="eng">The theory of electron spin-rotational (SR) relaxation in systems with an effective spin S eff = 1/2 is formulated in terms of the adiabaticr otation of effective spin (ARES) approach. It is shown that SR relaxation results from the orientational random walk of the axes of the intramolecular electric field potential (ligand field) to which a spin-bearing atomic center is exposed. The validity of the stochastict reatmentp resented here is not limited by the Redfield conditions. The general expression obtained for the time constant of electrons pin relaxation in liquid phase reproduces the well-known result of Hubbard-Atkins-Kivelson theory if it is specialized to the case of systems with weak spin-orbit coupling.</dcterms:abstract> </rdf:Description> </rdf:RDF>

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