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Alpha-Thioalkylation of Zinc Dienolates to 4-Substituted 1-tert-Butoxy-7a-methyl-hexahydroinden-5-ones

Alpha-Thioalkylation of Zinc Dienolates to 4-Substituted 1-tert-Butoxy-7a-methyl-hexahydroinden-5-ones

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GROTH, Ulrich, Thomas KÖHLER, Thomas TAAPKEN, 1994. Alpha-Thioalkylation of Zinc Dienolates to 4-Substituted 1-tert-Butoxy-7a-methyl-hexahydroinden-5-ones. In: Liebigs Annalen der Chemie(7), pp. 665-668

@article{Groth1994Alpha-9739, title={Alpha-Thioalkylation of Zinc Dienolates to 4-Substituted 1-tert-Butoxy-7a-methyl-hexahydroinden-5-ones}, year={1994}, number={7}, journal={Liebigs Annalen der Chemie}, pages={665--668}, author={Groth, Ulrich and Köhler, Thomas and Taapken, Thomas} }

<rdf:RDF xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns:bibo="http://purl.org/ontology/bibo/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:dcterms="http://purl.org/dc/terms/" xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > <rdf:Description rdf:about="https://kops.uni-konstanz.de/rdf/resource/123456789/9739"> <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T18:14:03Z</dcterms:available> <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T18:14:03Z</dc:date> <dc:format>application/pdf</dc:format> <dcterms:abstract xml:lang="deu">α-Alkylation of the α,β-unsaturated ketone 1 at C-4 has been achieved by thioalkylation of the corresponding zinc dienolate with α-chlorosulfides of type 2. The desulfurization of the β-(phenylthio) ketones 4 leads directly to the 4-substituted hexahydroinden-5-ones 5.</dcterms:abstract> <dc:language>eng</dc:language> <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/9739"/> <dcterms:issued>1994</dcterms:issued> <dc:contributor>Köhler, Thomas</dc:contributor> <dcterms:title>Alpha-Thioalkylation of Zinc Dienolates to 4-Substituted 1-tert-Butoxy-7a-methyl-hexahydroinden-5-ones</dcterms:title> <dc:creator>Groth, Ulrich</dc:creator> <dc:creator>Köhler, Thomas</dc:creator> <dc:creator>Taapken, Thomas</dc:creator> <dc:rights>deposit-license</dc:rights> <dc:contributor>Taapken, Thomas</dc:contributor> <dc:contributor>Groth, Ulrich</dc:contributor> <dcterms:rights rdf:resource="https://creativecommons.org/licenses/by-nc-nd/2.0/legalcode"/> <dcterms:bibliographicCitation>First publ. in: Liebigs Annalen der Chemie 1994, 7, pp. 665-668</dcterms:bibliographicCitation> </rdf:Description> </rdf:RDF>

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