Diastereoselective addition of organocerium(III) reagents derived from 3-substituted propargyl bromides to aldehydes
| Type of Publication: | Journal article |
| URI (citable link): | http://nbn-resolving.de/urn:nbn:de:bsz:352-opus-46020 |
| Author: | Groth, Ulrich; Kesenheimer, Christian; Neidhöfer, Jürgen |
| Year of publication: | 2006 |
| Published in: | Synlett ; 2006 (2006), 12. - pp. 1859-1862. - ISSN 0936-5214. - eISSN 1437-2096 |
| DOI (citable link): | https://dx.doi.org/10.1055/s-2006-947349 |
| Summary: |
Various cerium allenyl reagents were generated by transmetallation of allenyl Grignard compounds with CeCl3 and subsequent conversion into homopropargylic alcohols by addition to various aliphatic and aromatic aldehydes. The α-acetylenic alcohols were obtained with regioselectivities and diastereoselectivities up to 98% de in favor of the threo-diastereomers.
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| Subject (DDC): | 540 Chemistry |
| Keywords: | lanthanides, organometallic reagents, addition reactions, diastereoselectivity, regioselectivity |
| Link to License: | Terms of use |
| Bibliography of Konstanz: | Yes |
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GROTH, Ulrich, Christian KESENHEIMER, Jürgen NEIDHÖFER, 2006. Diastereoselective addition of organocerium(III) reagents derived from 3-substituted propargyl bromides to aldehydes. In: Synlett. 2006(12), pp. 1859-1862. ISSN 0936-5214. eISSN 1437-2096. Available under: doi: 10.1055/s-2006-947349
@article{Groth2006Diast-9721, title={Diastereoselective addition of organocerium(III) reagents derived from 3-substituted propargyl bromides to aldehydes}, year={2006}, doi={10.1055/s-2006-947349}, number={12}, volume={2006}, issn={0936-5214}, journal={Synlett}, pages={1859--1862}, author={Groth, Ulrich and Kesenheimer, Christian and Neidhöfer, Jürgen} }
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