On alkylideneamidosulfenyl chlorides and 1-Thia-2-azoniaallene salts

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WIRSCHUN, Wolfgang G., Martin G. HITZLER, Johannes C. JOCHIMS, Ulrich GROTH, 2002. <i>On alkylideneamidosulfenyl chlorides and 1-Thia-2-azoniaallene salts</i>. In: Helvetica chimica acta. <b>85</b>(9), pp. 2627-2635. ISSN 0018-019X. eISSN 1522-2675. Available under: doi: 10.1002/1522-2675(200209)85:9<2627::AID-HLCA2627>3.0.CO;2-H

@article{Wirschun2002alkyl-9698, title={On alkylideneamidosulfenyl chlorides and 1-Thia-2-azoniaallene salts}, year={2002}, doi={10.1002/1522-2675(200209)85:9<2627::AID-HLCA2627>3.0.CO;2-H}, number={9}, volume={85}, issn={0018-019X}, journal={Helvetica chimica acta}, pages={2627--2635}, author={Wirschun, Wolfgang G. and Hitzler, Martin G. and Jochims, Johannes C. and Groth, Ulrich} }

<rdf:RDF xmlns:dcterms="http://purl.org/dc/terms/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns:bibo="http://purl.org/ontology/bibo/" xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#" xmlns:foaf="http://xmlns.com/foaf/0.1/" xmlns:void="http://rdfs.org/ns/void#" xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > <rdf:Description rdf:about="https://kops.uni-konstanz.de/rdf/resource/123456789/9698"> <dc:creator>Wirschun, Wolfgang G.</dc:creator> <dc:creator>Hitzler, Martin G.</dc:creator> <dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/rdf/resource/123456789/29"/> <dcterms:title>On alkylideneamidosulfenyl chlorides and 1-Thia-2-azoniaallene salts</dcterms:title> <dc:format>application/pdf</dc:format> <dc:language>eng</dc:language> <dcterms:hasPart rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/9698/1/On_alkylideneamidosulfenyl_chlorides.pdf"/> <dc:contributor>Wirschun, Wolfgang G.</dc:contributor> <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/9698"/> <foaf:homepage rdf:resource="http://localhost:8080/jspui"/> <dcterms:bibliographicCitation>First publ. in: Helvetica chimica acta ; 85 (2002), 9. - S. 2627 - 2635</dcterms:bibliographicCitation> <void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/> <dc:contributor>Groth, Ulrich</dc:contributor> <dcterms:abstract xml:lang="eng">X-Ray-diffraction analysis of tBu2CNSCl (4b) revealed an almost linear CNS unit with an SN bond order of ca. 1.9 (Fig. 1), in agreement with the structure of a 1-thia-2-azoniaallene chloride. With SCl2 and SbCl5, compound 4b was transformed into the imidosulfurous dichloride 6 (Scheme 2). With morpholine, compounds 4b and 6 afforded the sulfenamide 7and the aminosulfonium salt 8, respectively. The (diarylmethylene)amidosulfenyl chlorides 4g,h,i reacted with SbCl5 to give SbCl salts of the 1,2-benzisothiazoles 9a,b,d, most likely via 1-thia-2-azoniaallene intermediates 2 (Scheme 3).</dcterms:abstract> <dc:creator>Jochims, Johannes C.</dc:creator> <dspace:hasBitstream rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/9698/1/On_alkylideneamidosulfenyl_chlorides.pdf"/> <dcterms:issued>2002</dcterms:issued> <dc:contributor>Jochims, Johannes C.</dc:contributor> <dc:creator>Groth, Ulrich</dc:creator> <dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/rdf/resource/123456789/29"/> <dc:rights>deposit-license</dc:rights> <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T18:13:47Z</dcterms:available> <dcterms:rights rdf:resource="https://creativecommons.org/licenses/by-nc-nd/2.0/legalcode"/> <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T18:13:47Z</dc:date> <dc:contributor>Hitzler, Martin G.</dc:contributor> </rdf:Description> </rdf:RDF>

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