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Cobalt mediated intramolecular [2+2+2]-cycloaddition of enediynes ­towards linear annelated polycycles

Cobalt mediated intramolecular [2+2+2]-cycloaddition of enediynes ­towards linear annelated polycycles

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ECKENBERG, Peter, Ulrich GROTH, 2003. Cobalt mediated intramolecular [2+2+2]-cycloaddition of enediynes ­towards linear annelated polycycles. In: Synlett. 23(14), pp. 2188-2192. ISSN 0570-0833. eISSN 1521-3773. Available under: doi: 10.1002/anie.198405393

@article{Eckenberg2003Cobal-9632, title={Cobalt mediated intramolecular [2+2+2]-cycloaddition of enediynes ­towards linear annelated polycycles}, year={2003}, doi={10.1002/anie.198405393}, number={14}, volume={23}, issn={0570-0833}, journal={Synlett}, pages={2188--2192}, author={Eckenberg, Peter and Groth, Ulrich} }

<rdf:RDF xmlns:dcterms="http://purl.org/dc/terms/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns:bibo="http://purl.org/ontology/bibo/" xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#" xmlns:foaf="http://xmlns.com/foaf/0.1/" xmlns:void="http://rdfs.org/ns/void#" xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > <rdf:Description rdf:about="https://kops.uni-konstanz.de/rdf/resource/123456789/9632"> <dcterms:issued>2003</dcterms:issued> <dc:creator>Eckenberg, Peter</dc:creator> <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/9632"/> <dc:rights>deposit-license</dc:rights> <dcterms:title>Cobalt mediated intramolecular [2+2+2]-cycloaddition of enediynes ­towards linear annelated polycycles</dcterms:title> <dcterms:rights rdf:resource="https://creativecommons.org/licenses/by-nc-nd/2.0/legalcode"/> <dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/rdf/resource/123456789/29"/> <void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/> <foaf:homepage rdf:resource="http://localhost:8080/jspui"/> <dcterms:bibliographicCitation>First publ. in: Synlett 2003, 14, pp. 2188-2192</dcterms:bibliographicCitation> <dcterms:hasPart rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/9632/1/Cobalt_mediated_intramolecular.pdf"/> <dc:language>eng</dc:language> <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T18:13:19Z</dc:date> <dc:creator>Groth, Ulrich</dc:creator> <dcterms:abstract xml:lang="eng">The cobalt mediated [2+2+2]-cycloaddition of enediynes 13 and 18 affords linear annelated polycycles such as the hexahydro naphthalene 14 and the decahydro anthracene 19. This latter compound can be transformed into the enantiomerically pure anthracene derivative 21 in only two reaction steps. 1,9,10-Trihydroxy octahydro anthracene (21) represents the ABC-framework of many anthracycline antibiotics such as the antitumor active daunomycine.</dcterms:abstract> <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T18:13:19Z</dcterms:available> <dspace:hasBitstream rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/9632/1/Cobalt_mediated_intramolecular.pdf"/> <dc:contributor>Eckenberg, Peter</dc:contributor> <dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/rdf/resource/123456789/29"/> <dc:contributor>Groth, Ulrich</dc:contributor> <dc:format>application/pdf</dc:format> </rdf:Description> </rdf:RDF>

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