Cross-metathesis of vinylsilanes with olefins in the presence of Grubbs catalyst

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PIETRASZUK, Cezary, Helmut FISCHER, Malgorzata KUJAWA, Bogdan MARCINIEC, 2001. Cross-metathesis of vinylsilanes with olefins in the presence of Grubbs catalyst. In: Tetrahedron Letters. 42(6), pp. 1175-1178. ISSN 0040-4039. Available under: doi: 10.1016/S0040-4039(00)02201-2

@article{Pietraszuk2001Cross-9627, title={Cross-metathesis of vinylsilanes with olefins in the presence of Grubbs catalyst}, year={2001}, doi={10.1016/S0040-4039(00)02201-2}, number={6}, volume={42}, issn={0040-4039}, journal={Tetrahedron Letters}, pages={1175--1178}, author={Pietraszuk, Cezary and Fischer, Helmut and Kujawa, Malgorzata and Marciniec, Bogdan} }

<rdf:RDF xmlns:dcterms="http://purl.org/dc/terms/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns:bibo="http://purl.org/ontology/bibo/" xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#" xmlns:foaf="http://xmlns.com/foaf/0.1/" xmlns:void="http://rdfs.org/ns/void#" xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > <rdf:Description rdf:about="https://kops.uni-konstanz.de/rdf/resource/123456789/9627"> <dc:format>application/pdf</dc:format> <dcterms:abstract xml:lang="eng">Effective cross-metathesis of H2C=C(H)SiR3, where SiR3=Si(OMe)3, Si(OEt)3, Si(OSiMe3)3, with selected olefins in the presence of (PCy3)2Cl2Ru(=CHPh) (I) is described. Treatment of p-substituted styrenes, 1-alkenes and selected allyl derivatives H2C=CHCH2R' (R'=SiMe3, Si(OEt)3, Ph, OPh) with an excess of H2C=C(H)SiR3 results in the formation of the respective cross-metathesis products with good yields and selectivities. The metallacarbene mechanism of the process is discussed.</dcterms:abstract> <dc:creator>Marciniec, Bogdan</dc:creator> <dc:rights>deposit-license</dc:rights> <foaf:homepage rdf:resource="http://localhost:8080/jspui"/> <dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/rdf/resource/123456789/29"/> <dc:contributor>Fischer, Helmut</dc:contributor> <dc:contributor>Marciniec, Bogdan</dc:contributor> <dcterms:hasPart rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/9627/1/TL_01_42_1175.pdf"/> <dcterms:title>Cross-metathesis of vinylsilanes with olefins in the presence of Grubbs catalyst</dcterms:title> <dcterms:rights rdf:resource="https://creativecommons.org/licenses/by-nc-nd/2.0/legalcode"/> <dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/rdf/resource/123456789/29"/> <dspace:hasBitstream rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/9627/1/TL_01_42_1175.pdf"/> <dc:contributor>Pietraszuk, Cezary</dc:contributor> <dc:language>eng</dc:language> <void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/> <dc:creator>Kujawa, Malgorzata</dc:creator> <dc:creator>Pietraszuk, Cezary</dc:creator> <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/9627"/> <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T18:13:17Z</dc:date> <dc:contributor>Kujawa, Malgorzata</dc:contributor> <dcterms:bibliographicCitation>First publ. in: Tetrahedron Letters 42 (2001), pp. 1175 1178</dcterms:bibliographicCitation> <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T18:13:17Z</dcterms:available> <dc:creator>Fischer, Helmut</dc:creator> <dcterms:issued>2001</dcterms:issued> </rdf:Description> </rdf:RDF>

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