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Oxidative Perhydroxylation of [closo-B12H12]2- ; to the Stable Inorganic Cluster Redox System [B12(OH)12]2-l.- : Experiment and Theory

Oxidative Perhydroxylation of [closo-B12H12]2- ; to the Stable Inorganic Cluster Redox System [B12(OH)12]2-l.- : Experiment and Theory

Publikationstyp: Zeitschriftenartikel
URI (zitierfähiger Link): http://nbn-resolving.de/urn:nbn:de:bsz:352-opus-129034
Autor/innen: Van, Nguyen; Tiritiris, Ioannis; Winter, Rainer F.; Sarkar, Biprajit; Singh, Priti; Duboc, Carole; Muñoz-Castro, Alvaro; Arratia-Pérez, Ramiro; Kaim, Wolfgang; Schleid, Thomas
Erscheinungsjahr: 2010
Erschienen in: Chemistry: a European Journal ; 16 (2010), 37. - S. 11242-11245. - eISSN 0947-6539
Pubmed ID: 20726020
DOI (zitierfähiger Link): https://dx.doi.org/10.1002/chem.201001374
Zusammenfassung:
It′s radical: A surprisingly simple reaction converts the normally inert prototypical hydridoborate cluster [closo-B12H12]2− not only to [closo-B12(OH)12]2− but also, at less-elevated temperatures, to the new [hypocloso-B12(OH)12].− radical anion (see figure). Both approximately icosahedral closo and hypocloso cluster ions were structurally characterized as the cesium salts and their properties were assessed experimentally and theoretically.
Fachgebiet (DDC): 540 Chemie
Schlagwörter: borates, cage compounds, closomers, electron-deficient compounds, hydroxylation, radicals
Link zur Lizenz: Deposit-Lizenz
Universitätsbibliographie: Ja

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VAN, Nguyen, Ioannis TIRITIRIS, Rainer F. WINTER, Biprajit SARKAR, Priti SINGH, Carole DUBOC, Alvaro MUÑOZ-CASTRO, Ramiro ARRATIA-PÉREZ, Wolfgang KAIM, Thomas SCHLEID, 2010. Oxidative Perhydroxylation of [closo-B12H12]2- ; to the Stable Inorganic Cluster Redox System [B12(OH)12]2-l.- : Experiment and Theory. In: Chemistry: a European Journal. 16(37), pp. 11242-11245. eISSN 0947-6539

@article{Van2010Oxida-9599, title={Oxidative Perhydroxylation of [closo-B12H12]2- ; to the Stable Inorganic Cluster Redox System [B12(OH)12]2-l.- : Experiment and Theory}, year={2010}, doi={10.1002/chem.201001374}, number={37}, volume={16}, journal={Chemistry: a European Journal}, pages={11242--11245}, author={Van, Nguyen and Tiritiris, Ioannis and Winter, Rainer F. and Sarkar, Biprajit and Singh, Priti and Duboc, Carole and Muñoz-Castro, Alvaro and Arratia-Pérez, Ramiro and Kaim, Wolfgang and Schleid, Thomas} }

Schleid, Thomas Muñoz-Castro, Alvaro Arratia-Pérez, Ramiro application/pdf Duboc, Carole First publ. in: Chemistry: a European Journal 16 (2010), 37, pp. 11242-11245 Schleid, Thomas Winter, Rainer F. 2011-03-24T18:13:03Z Duboc, Carole Kaim, Wolfgang Singh, Priti Winter, Rainer F. Tiritiris, Ioannis Oxidative Perhydroxylation of [closo-B12H12]2- ; to the Stable Inorganic Cluster Redox System [B12(OH)12]2-l.- : Experiment and Theory 2011-05-03T08:53:16Z Sarkar, Biprajit Arratia-Pérez, Ramiro 2010 Tiritiris, Ioannis Singh, Priti Van, Nguyen Muñoz-Castro, Alvaro eng Van, Nguyen Kaim, Wolfgang Sarkar, Biprajit <b>It&#8242;s radical</b>: A surprisingly simple reaction converts the normally inert prototypical hydridoborate cluster [<em>closo</em>-B<sub>12</sub>H<sub>12</sub>]<sup>2&#8722;</sup> not only to [<em>closo</em>-B<sub>12</sub>(OH)<sub>12</sub>]<sup>2&#8722;</sup> but also, at less-elevated temperatures, to the new [<em>hypocloso</em>-B<sub>12</sub>(OH)<sub>12</sub>]<sup>.&#8722;</sup> radical anion (see figure). Both approximately icosahedral <em>closo</em> and <em>hypocloso</em> cluster ions were structurally characterized as the cesium salts and their properties were assessed experimentally and theoretically. deposit-license

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