Aufgrund von Vorbereitungen auf eine neue Version von KOPS, können kommenden Montag und Dienstag keine Publikationen eingereicht werden. (Due to preparations for a new version of KOPS, no publications can be submitted next Monday and Tuesday.)
Type of Publication: | Journal article |
URI (citable link): | http://nbn-resolving.de/urn:nbn:de:bsz:352-opus-129034 |
Author: | Van, Nguyen; Tiritiris, Ioannis; Winter, Rainer F.; Sarkar, Biprajit; Singh, Priti; Duboc, Carole; Muñoz-Castro, Alvaro; Arratia-Pérez, Ramiro; Kaim, Wolfgang; Schleid, Thomas |
Year of publication: | 2010 |
Published in: | Chemistry: a European Journal ; 16 (2010), 37. - pp. 11242-11245. - eISSN 0947-6539 |
Pubmed ID: | 20726020 |
DOI (citable link): | https://dx.doi.org/10.1002/chem.201001374 |
Summary: |
It′s radical: A surprisingly simple reaction converts the normally inert prototypical hydridoborate cluster [closo-B12H12]2− not only to [closo-B12(OH)12]2− but also, at less-elevated temperatures, to the new [hypocloso-B12(OH)12].− radical anion (see figure). Both approximately icosahedral closo and hypocloso cluster ions were structurally characterized as the cesium salts and their properties were assessed experimentally and theoretically.
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Subject (DDC): | 540 Chemistry |
Keywords: | borates, cage compounds, closomers, electron-deficient compounds, hydroxylation, radicals |
Link to License: | In Copyright |
Bibliography of Konstanz: | Yes |
VAN, Nguyen, Ioannis TIRITIRIS, Rainer F. WINTER, Biprajit SARKAR, Priti SINGH, Carole DUBOC, Alvaro MUÑOZ-CASTRO, Ramiro ARRATIA-PÉREZ, Wolfgang KAIM, Thomas SCHLEID, 2010. Oxidative Perhydroxylation of [closo-B12H12]2- ; to the Stable Inorganic Cluster Redox System [B12(OH)12]2-/.- : Experiment and Theory. In: Chemistry: a European Journal. 16(37), pp. 11242-11245. eISSN 0947-6539. Available under: doi: 10.1002/chem.201001374
@article{Van2010Oxida-9599, title={Oxidative Perhydroxylation of [closo-B12H12]2- ; to the Stable Inorganic Cluster Redox System [B12(OH)12]2-/.- : Experiment and Theory}, year={2010}, doi={10.1002/chem.201001374}, number={37}, volume={16}, journal={Chemistry: a European Journal}, pages={11242--11245}, author={Van, Nguyen and Tiritiris, Ioannis and Winter, Rainer F. and Sarkar, Biprajit and Singh, Priti and Duboc, Carole and Muñoz-Castro, Alvaro and Arratia-Pérez, Ramiro and Kaim, Wolfgang and Schleid, Thomas} }
Schleid_Winter_CEJ_2010.pdf | 1144 |