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Kinetic study of the photodecoloration mechanism of an inversely photochromic class of compounds forming spiropyran analogues

Kinetic study of the photodecoloration mechanism of an inversely photochromic class of compounds forming spiropyran analogues

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KÜHN, Dietmar, Heinz BALLI, Ulrich STEINER, 1991. Kinetic study of the photodecoloration mechanism of an inversely photochromic class of compounds forming spiropyran analogues. In: Journal of photochemistry and photobiology A: Chemistry. 61(1), pp. 99-112. ISSN 1010-6030

@article{Kuhn1991Kinet-9591, title={Kinetic study of the photodecoloration mechanism of an inversely photochromic class of compounds forming spiropyran analogues}, year={1991}, doi={10.1016/1010-6030(91)85078-U}, number={1}, volume={61}, issn={1010-6030}, journal={Journal of photochemistry and photobiology A: Chemistry}, pages={99--112}, author={Kühn, Dietmar and Balli, Heinz and Steiner, Ulrich} }

<rdf:RDF xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns:bibo="http://purl.org/ontology/bibo/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:dcterms="http://purl.org/dc/terms/" xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > <rdf:Description rdf:about="https://kops.uni-konstanz.de/rdf/resource/123456789/9591"> <dcterms:rights rdf:resource="https://creativecommons.org/licenses/by-nc-nd/2.0/legalcode"/> <dc:contributor>Steiner, Ulrich</dc:contributor> <dc:format>application/pdf</dc:format> <dc:contributor>Balli, Heinz</dc:contributor> <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/9591"/> <dcterms:bibliographicCitation>First publ. in: Journal of photochemistry and photobiology A: Chemistry 61 (1991), 1, pp. 99-112</dcterms:bibliographicCitation> <dc:creator>Steiner, Ulrich</dc:creator> <dc:creator>Balli, Heinz</dc:creator> <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T18:12:58Z</dc:date> <dc:rights>deposit-license</dc:rights> <dcterms:title>Kinetic study of the photodecoloration mechanism of an inversely photochromic class of compounds forming spiropyran analogues</dcterms:title> <dc:language>eng</dc:language> <dc:creator>Kühn, Dietmar</dc:creator> <dcterms:issued>1991</dcterms:issued> <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T18:12:58Z</dcterms:available> <dcterms:abstract xml:lang="eng">The quantum yields and kinetics of the photodecoloration of five representatives of an inversely photochromic class of compounds, reacting to give spiro compounds related to the indolinospiropyrans by replacement of the chromene part of the molecule by an imidazodihydroquinoline fragment, were investigated by stationary illumination and nanosecond time-resolved laser flash spectroscopy. In particular, the role of the ground state of the open-chain cis conformer as an intermediate in spiro-bond formation (photodecoloration) and opening (thermocoloration) was quantitatively assessed.</dcterms:abstract> <dc:contributor>Kühn, Dietmar</dc:contributor> </rdf:Description> </rdf:RDF>

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