Si-C bond activation in the reaction of first generation Grubbs' catalyst with alkynylsilanes - formation of [Cl2{P(C6H11)3}2Ru(=CHCH=CHPh)] and disiloxanes

Powala, Beata; Fischer, Helmut; Pietraszuk, Cezary

Si-C bond activation in the reaction of first generation Grubbs' catalyst with alkynylsilanes - formation of [Cl2{P(C6H11)3}2Ru(=CHCH=CHPh)] and disiloxanes

Dateien

12983t.pdfGröße: 212.68 KBDownloads: 512

Datum

2010

Autor:innen

Powala, Beata

Fischer, Helmut

Pietraszuk, Cezary

Open Access-Veröffentlichung

Open Access Green

Sammlungen

Chemie

Publikationstyp

Zeitschriftenartikel

Publikationsstatus

Published

Erschienen in

Dalton transactions. 2010, 39(8), pp. 1923-1925. ISSN 1477-9226. eISSN 1477-9234. Available under: doi: 10.1039/B924945C

Zusammenfassung

The first generation Grubbs catalyst [Cl2{P(C6H11)3}2Ru=C(H)Ph] reacts efficiently with alkynylsilanes in the presence of water to give the styryl carbene complex [Cl2{P(C6H11)}2Ru=C(CH=CHPh)H] and disiloxane.

Fachgebiet (DDC)

540 Chemie

Zitieren

ISO 690

POWALA, Beata, Helmut FISCHER, Cezary PIETRASZUK, 2010. Si-C bond activation in the reaction of first generation Grubbs' catalyst with alkynylsilanes - formation of [Cl2{P(C6H11)3}2Ru(=CHCH=CHPh)] and disiloxanes. In: Dalton transactions. 2010, 39(8), pp. 1923-1925. ISSN 1477-9226. eISSN 1477-9234. Available under: doi: 10.1039/B924945C

BibTex

@article{Powala2010activ-9578,
  year={2010},
  doi={10.1039/B924945C},
  title={Si-C bond activation in the reaction of first generation Grubbs' catalyst with alkynylsilanes - formation of [Cl2{P(C6H11)3}2Ru(=CHCH=CHPh)] and disiloxanes},
  number={8},
  volume={39},
  issn={1477-9226},
  journal={Dalton transactions},
  pages={1923--1925},
  author={Powala, Beata and Fischer, Helmut and Pietraszuk, Cezary}
}

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