Mesosynthesis of ZnO-Silica Composites for Methanol Nanocatalysis

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POLARZ, Sebastian, F. NEUES, Maurits W. E. van den BERG, Wolfgang GRÜNERT, Lamma KHODEIR, 2005. Mesosynthesis of ZnO-Silica Composites for Methanol Nanocatalysis. In: Journal of the American Chemical Society. 127(34), pp. 12028-12034. ISSN 0002-7863. eISSN 1520-5126

@article{Polarz2005Mesos-9563, title={Mesosynthesis of ZnO-Silica Composites for Methanol Nanocatalysis}, year={2005}, doi={10.1021/ja0516514}, number={34}, volume={127}, issn={0002-7863}, journal={Journal of the American Chemical Society}, pages={12028--12034}, author={Polarz, Sebastian and Neues, F. and Berg, Maurits W. E. van den and Grünert, Wolfgang and Khodeir, Lamma} }

<rdf:RDF xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns:bibo="http://purl.org/ontology/bibo/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:dcterms="http://purl.org/dc/terms/" xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > <rdf:Description rdf:about="https://kops.uni-konstanz.de/rdf/resource/123456789/9563"> <dc:language>eng</dc:language> <dc:contributor>Neues, F.</dc:contributor> <dc:creator>Polarz, Sebastian</dc:creator> <dc:creator>Neues, F.</dc:creator> <dc:rights>deposit-license</dc:rights> <dc:creator>Berg, Maurits W. E. van den</dc:creator> <dcterms:abstract xml:lang="eng">Methanol catalysis meets chemistry under confined conditions. Methanol is regarded as one of the most important future energy sources. ZnO/Cu composite materials are very effective in heterogeneous catalysis for methanol production due to the so-called strong metal-support interaction effect (SMSI). Therefore, materials of superior structural design potentially representing model systems for heterogeneous catalysis are highly desired. Ultimately, such materials could help to understand the interaction between copper and zinc oxide in more detail than currently possible. We report the preparation of nanocrystalline, size-selected ZnO inside the pore system of ordered mesoporous silica materials. A new, liquid precursor for ZnO is introduced. It is seen that the spatial confinement significantly influences the chemical properties of the precursor as well as determines a hierarchical architecture of the final ZnO/SiO2 nanocomposites. Finally, the ability of the materials to act as model systems in methanol preparation is investigated. The materials are characterized by a variety of techniques including electron microscopy, X-ray scattering, solidstate NMR, EPR, EXAFS, and Raman spectroscopy, and physisorption analysis.</dcterms:abstract> <dc:contributor>Berg, Maurits W. E. van den</dc:contributor> <dcterms:issued>2005</dcterms:issued> <dcterms:rights rdf:resource="https://creativecommons.org/licenses/by-nc-nd/2.0/legalcode"/> <dc:contributor>Polarz, Sebastian</dc:contributor> <dcterms:bibliographicCitation>First publ. in: Journal of the American Chemical Society ; 127 (2005), 34. - S. 12028-12034</dcterms:bibliographicCitation> <dcterms:title>Mesosynthesis of ZnO-Silica Composites for Methanol Nanocatalysis</dcterms:title> <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T18:12:47Z</dc:date> <dc:contributor>Khodeir, Lamma</dc:contributor> <dc:creator>Grünert, Wolfgang</dc:creator> <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/9563"/> <dc:contributor>Grünert, Wolfgang</dc:contributor> <dc:format>application/pdf</dc:format> <dc:creator>Khodeir, Lamma</dc:creator> </rdf:Description> </rdf:RDF>

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