Thionine triplet relaxation in pyridine : a completely time-resolved förster cycle
| Type of Publication: | Journal article |
| URI (citable link): | http://nbn-resolving.de/urn:nbn:de:bsz:352-opus-49168 |
| Author: | Eipper, Hartmut; Abdel-Kader, Mahmoud H.; Kramer, Horst E. A.; Steiner, Ulrich |
| Year of publication: | 1985 |
| Published in: | Journal of Photochemistry ; 28 (1985), 3. - pp. 433-441. - ISSN 0047-2670 |
| DOI (citable link): | https://dx.doi.org/10.1016/0047-2670(85)85045-0 |
| Summary: |
The deactivation pathway of the thionine triplet (3 TH +) in pyridine was investigated using microsecond laser flash spectroscopy. It was found that the electronic relaxation of the triplet 3 TH + occurs via protolytic dissociation to the triplet 3 T which, after radiationless decay to the ground state T, is reprotonated to TH +. The unique feature of this deactivation pathway is that is represents a Förster cycle where all steps can be conveniently followed by flash spectroscopy in the microsecond time regime. The energy of the triplet state 3 T was estimated to be 150 ± 6 kJ mol -1.
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| Subject (DDC): | 540 Chemistry |
| Link to License: | In Copyright |
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EIPPER, Hartmut, Mahmoud H. ABDEL-KADER, Horst E. A. KRAMER, Ulrich STEINER, 1985. Thionine triplet relaxation in pyridine : a completely time-resolved förster cycle. In: Journal of Photochemistry. 28(3), pp. 433-441. ISSN 0047-2670. Available under: doi: 10.1016/0047-2670(85)85045-0
@article{Eipper1985Thion-9536, title={Thionine triplet relaxation in pyridine : a completely time-resolved förster cycle}, year={1985}, doi={10.1016/0047-2670(85)85045-0}, number={3}, volume={28}, issn={0047-2670}, journal={Journal of Photochemistry}, pages={433--441}, author={Eipper, Hartmut and Abdel-Kader, Mahmoud H. and Kramer, Horst E. A. and Steiner, Ulrich} }
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