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Thionine triplet relaxation in pyridine : a completely time-resolved förster cycle

Thionine triplet relaxation in pyridine : a completely time-resolved förster cycle

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EIPPER, Hartmut, Mahmoud H. ABDEL-KADER, Horst E. A. KRAMER, Ulrich STEINER, 1985. Thionine triplet relaxation in pyridine : a completely time-resolved förster cycle. In: Journal of Photochemistry. 28(3), pp. 433-441. ISSN 0047-2670

@article{Eipper1985Thion-9536, title={Thionine triplet relaxation in pyridine : a completely time-resolved förster cycle}, year={1985}, doi={10.1016/0047-2670(85)85045-0}, number={3}, volume={28}, issn={0047-2670}, journal={Journal of Photochemistry}, pages={433--441}, author={Eipper, Hartmut and Abdel-Kader, Mahmoud H. and Kramer, Horst E. A. and Steiner, Ulrich} }

<rdf:RDF xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns:bibo="http://purl.org/ontology/bibo/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:dcterms="http://purl.org/dc/terms/" xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > <rdf:Description rdf:about="https://kops.uni-konstanz.de/rdf/resource/123456789/9536"> <dc:contributor>Abdel-Kader, Mahmoud H.</dc:contributor> <dcterms:bibliographicCitation>First publ. in: Journal of Photochemistry 28 (1985), 3, pp. 433-441</dcterms:bibliographicCitation> <dcterms:issued>1985</dcterms:issued> <dc:rights>deposit-license</dc:rights> <dc:contributor>Eipper, Hartmut</dc:contributor> <dcterms:abstract xml:lang="eng">The deactivation pathway of the thionine triplet (3 TH +) in pyridine was investigated using microsecond laser flash spectroscopy. It was found that the electronic relaxation of the triplet 3 TH + occurs via protolytic dissociation to the triplet 3 T which, after radiationless decay to the ground state T, is reprotonated to TH +. The unique feature of this deactivation pathway is that is represents a Förster cycle where all steps can be conveniently followed by flash spectroscopy in the microsecond time regime. The energy of the triplet state 3 T was estimated to be 150 ± 6 kJ mol -1.</dcterms:abstract> <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T18:12:33Z</dc:date> <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/9536"/> <dc:creator>Kramer, Horst E. A.</dc:creator> <dc:language>eng</dc:language> <dc:creator>Abdel-Kader, Mahmoud H.</dc:creator> <dc:creator>Steiner, Ulrich</dc:creator> <dc:contributor>Steiner, Ulrich</dc:contributor> <dc:format>application/pdf</dc:format> <dc:creator>Eipper, Hartmut</dc:creator> <dcterms:title>Thionine triplet relaxation in pyridine : a completely time-resolved förster cycle</dcterms:title> <dcterms:rights rdf:resource="https://creativecommons.org/licenses/by-nc-nd/2.0/legalcode"/> <dc:contributor>Kramer, Horst E. A.</dc:contributor> <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T18:12:33Z</dcterms:available> </rdf:Description> </rdf:RDF>

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