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Appearance of bulk properties in small tungsten oxide clusters

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SUN, Qiang, Bijan K. RAO, Purusottam JENA, Davor STOLCIC, Young Dok KIM, Gerd GANTEFÖR, Albert Welford CASTLEMAN, 2004. Appearance of bulk properties in small tungsten oxide clusters. In: Journal of Chemical Physics. 121(19), pp. 9417-9422. Available under: doi: 10.1063/1.1807374

@article{Sun2004Appea-9438, title={Appearance of bulk properties in small tungsten oxide clusters}, year={2004}, doi={10.1063/1.1807374}, number={19}, volume={121}, journal={Journal of Chemical Physics}, pages={9417--9422}, author={Sun, Qiang and Rao, Bijan K. and Jena, Purusottam and Stolcic, Davor and Kim, Young Dok and Ganteför, Gerd and Castleman, Albert Welford} }

<rdf:RDF xmlns:dcterms="" xmlns:dc="" xmlns:rdf="" xmlns:bibo="" xmlns:dspace="" xmlns:foaf="" xmlns:void="" xmlns:xsd="" > <rdf:Description rdf:about=""> <dc:creator>Ganteför, Gerd</dc:creator> <dcterms:title>Appearance of bulk properties in small tungsten oxide clusters</dcterms:title> <dcterms:isPartOf rdf:resource=""/> <dc:creator>Jena, Purusottam</dc:creator> <dcterms:issued>2004</dcterms:issued> <dspace:isPartOfCollection rdf:resource=""/> <dc:creator>Rao, Bijan K.</dc:creator> <bibo:uri rdf:resource=""/> <dc:date rdf:datatype="">2011-03-24T17:56:31Z</dc:date> <foaf:homepage rdf:resource="http://localhost:8080/jspui"/> <dc:language>eng</dc:language> <dspace:isPartOfCollection rdf:resource=""/> <dc:contributor>Kim, Young Dok</dc:contributor> <dc:contributor>Stolcic, Davor</dc:contributor> <dcterms:rights rdf:resource=""/> <dcterms:available rdf:datatype="">2011-03-24T17:56:31Z</dcterms:available> <dc:creator>Castleman, Albert Welford</dc:creator> <dc:creator>Sun, Qiang</dc:creator> <dcterms:bibliographicCitation>First publ. in: Journal of Chemical Physics 121 (2004), 19, pp. 9417-9422</dcterms:bibliographicCitation> <dc:format>application/pdf</dc:format> <dspace:hasBitstream rdf:resource=""/> <dc:rights>terms-of-use</dc:rights> <dc:contributor>Castleman, Albert Welford</dc:contributor> <dcterms:isPartOf rdf:resource=""/> <dc:contributor>Ganteför, Gerd</dc:contributor> <void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/> <dc:creator>Stolcic, Davor</dc:creator> <dc:contributor>Jena, Purusottam</dc:contributor> <dc:creator>Kim, Young Dok</dc:creator> <dc:contributor>Rao, Bijan K.</dc:contributor> <dcterms:hasPart rdf:resource=""/> <dcterms:abstract xml:lang="eng">Contrary to the conventional understanding that atomic clusters usually differ in properties and structure from the bulk constituents of which they are comprised, we show that even a dimer of tungsten oxide (WO3)2 possesses bulklike features and the geometry of a small cluster containing only 4 tungsten and 12 oxygen atoms bears the hallmarks of crystalline tungsten oxide, WO3. This observation, based on a synergistic approach involving mass distributions under quasisteady state conditions, photoelectron spectroscopy, and first principles molecular orbital theory, not only illustrates the existence of a class of strongly covalent or ionic materials whose embryonic forms are tiny clusters but also lends the possibility that a fundamental understanding of complex processes such as catalytic reactions on surfaces may be achieved on an atomic scale with clusters as model systems.</dcterms:abstract> <dc:contributor>Sun, Qiang</dc:contributor> </rdf:Description> </rdf:RDF>

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