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Bonding of CO to metal particles : photoelectron spectra of Nin(CO)m- and Ptn(CO)m- clusters

Bonding of CO to metal particles : photoelectron spectra of Nin(CO)m- and Ptn(CO)m- clusters

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SCHULZE ICKING-KONERT, Georg, Haiko HANDSCHUH, Gerd GANTEFÖR, Wolfgang EBERHARDT, 1996. Bonding of CO to metal particles : photoelectron spectra of Nin(CO)m- and Ptn(CO)m- clusters. In: Physical Review Letters. 76(7), pp. 1047-1050

@article{Schulze Icking-Konert1996Bondi-9310, title={Bonding of CO to metal particles : photoelectron spectra of Nin(CO)m- and Ptn(CO)m- clusters}, year={1996}, doi={10.1103/PhysRevLett.76.1047}, number={7}, volume={76}, journal={Physical Review Letters}, pages={1047--1050}, author={Schulze Icking-Konert, Georg and Handschuh, Haiko and Ganteför, Gerd and Eberhardt, Wolfgang} }

<rdf:RDF xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns:bibo="http://purl.org/ontology/bibo/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:dcterms="http://purl.org/dc/terms/" xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > <rdf:Description rdf:about="https://kops.uni-konstanz.de/rdf/resource/123456789/9310"> <dc:creator>Schulze Icking-Konert, Georg</dc:creator> <dc:format>application/pdf</dc:format> <dc:contributor>Eberhardt, Wolfgang</dc:contributor> <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/9310"/> <dcterms:abstract xml:lang="eng">Photoelectron spectra of mass-selected negatively charged bare Nin - and Ptn - clusters are compared with the spectra of Nin(CO)m- and Ptn(CO)m - clusters. The spectra indicate that saturation with CO is caused by the formation of an electronic closed shell and not due to steric hindrance as on a surface, and that the strength of the π backdonation of the CO chemisorption bond to a small particle is stronger than to a surface. The antibonding metal (dz2-5σ) orbital resulting from the interaction of the CO 5σ with the metal dz2 orbitals is directly observed for Ni1(CO)3 -.</dcterms:abstract> <dc:rights>deposit-license</dc:rights> <dc:creator>Handschuh, Haiko</dc:creator> <dcterms:bibliographicCitation>First publ. in: Physical Review Letters 76 (1996), 7, pp. 1047-1050</dcterms:bibliographicCitation> <dc:language>eng</dc:language> <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T17:55:23Z</dcterms:available> <dc:creator>Ganteför, Gerd</dc:creator> <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T17:55:23Z</dc:date> <dc:contributor>Handschuh, Haiko</dc:contributor> <dcterms:rights rdf:resource="http://nbn-resolving.org/urn:nbn:de:bsz:352-20140905103416863-3868037-7"/> <dcterms:title>Bonding of CO to metal particles : photoelectron spectra of Nin(CO)m- and Ptn(CO)m- clusters</dcterms:title> <dc:creator>Eberhardt, Wolfgang</dc:creator> <dc:contributor>Schulze Icking-Konert, Georg</dc:contributor> <dcterms:issued>1996</dcterms:issued> <dc:contributor>Ganteför, Gerd</dc:contributor> </rdf:Description> </rdf:RDF>

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