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Structure of the oxygen adduct intermediate in the bacterialluciferase reaction : 13C nuclear magnetic resonance determination

Structure of the oxygen adduct intermediate in the bacterialluciferase reaction : 13C nuclear magnetic resonance determination

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GHISLA, Sandro, J. Woodland HASTINGS, Vincent FAVAUDON, Jean-Marc LHOSTE, 1978. Structure of the oxygen adduct intermediate in the bacterialluciferase reaction : 13C nuclear magnetic resonance determination. In: Proceedings of the National Academy of Science of the United States of America. 75(12), pp. 5860-5863

@article{Ghisla1978Struc-7556, title={Structure of the oxygen adduct intermediate in the bacterialluciferase reaction : 13C nuclear magnetic resonance determination}, year={1978}, number={12}, volume={75}, journal={Proceedings of the National Academy of Science of the United States of America}, pages={5860--5863}, author={Ghisla, Sandro and Hastings, J. Woodland and Favaudon, Vincent and Lhoste, Jean-Marc} }

<rdf:RDF xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns:bibo="http://purl.org/ontology/bibo/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:dcterms="http://purl.org/dc/terms/" xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > <rdf:Description rdf:about="https://kops.uni-konstanz.de/rdf/resource/123456789/7556"> <dc:rights>deposit-license</dc:rights> <dcterms:title>Structure of the oxygen adduct intermediate in the bacterialluciferase reaction : 13C nuclear magnetic resonance determination</dcterms:title> <dc:contributor>Favaudon, Vincent</dc:contributor> <dc:creator>Lhoste, Jean-Marc</dc:creator> <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T17:35:22Z</dcterms:available> <dcterms:abstract xml:lang="eng">By using FMN enriched in 13C (90%) at position C-4a, we have conclusively shown that the reaction of molecular oxygen with bacterial luciferase-bound FMNH2 forms an adduct at the 4a position. Consistent with this are 13C NMR studies of FMN and other flavin compounds which show that this carbon should be unusually reactive in the reduced 1,5-dihydroflavins with respect to electrophilic attacks.</dcterms:abstract> <dc:contributor>Lhoste, Jean-Marc</dc:contributor> <dc:creator>Ghisla, Sandro</dc:creator> <dc:contributor>Hastings, J. Woodland</dc:contributor> <dcterms:bibliographicCitation>First publ. in: Proceedings of the National Academy of Science of the United States of America 75 (1978), 12, pp. 5860-5863</dcterms:bibliographicCitation> <dc:creator>Favaudon, Vincent</dc:creator> <dcterms:rights rdf:resource="https://creativecommons.org/licenses/by-nc-nd/2.0/legalcode"/> <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T17:35:22Z</dc:date> <dc:creator>Hastings, J. Woodland</dc:creator> <dc:contributor>Ghisla, Sandro</dc:contributor> <dc:format>application/pdf</dc:format> <dcterms:issued>1978</dcterms:issued> <dc:language>eng</dc:language> <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/7556"/> </rdf:Description> </rdf:RDF>

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