Biotransformation of Chloromethane to Methanethiol


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STROMEYER, Susanna A., Alasdair M. COOK, Thomas LEISINGER, 1993. Biotransformation of Chloromethane to Methanethiol. In: Environmental Science and Technology. 27(8), pp. 1577-1579. ISSN 0013-936X. eISSN 1520-5851

@article{Stromeyer1993Biotr-7210, title={Biotransformation of Chloromethane to Methanethiol}, year={1993}, doi={10.1021/es00045a012}, number={8}, volume={27}, issn={0013-936X}, journal={Environmental Science and Technology}, pages={1577--1579}, author={Stromeyer, Susanna A. and Cook, Alasdair M. and Leisinger, Thomas} }

<rdf:RDF xmlns:rdf="" xmlns:bibo="" xmlns:dc="" xmlns:dcterms="" xmlns:xsd="" > <rdf:Description rdf:about=""> <dc:language>eng</dc:language> <bibo:uri rdf:resource=""/> <dc:contributor>Leisinger, Thomas</dc:contributor> <dc:creator>Cook, Alasdair M.</dc:creator> <dc:contributor>Stromeyer, Susanna A.</dc:contributor> <dcterms:rights rdf:resource=""/> <dcterms:abstract xml:lang="eng">Monochloromethane (MeCl) was biotransformed by a mixed culture of anaerobic bacteria which had been enriched to utilize dichloromethane as the sole source of carbon and energy. Cells grown in dichloromethane-salts medium catalyzed the transformation, whereas sucrose-grown cells were inactive. MeCl disappeared almost totally, and the methyl group was recovered in a yield of 80-90% as methanethiol and traces of dimethyl sulfide, whose identities were confirmed by GC-MS. The methyl transfer was heat-labile, and free aquocobalamin did not promote the reaction, which was apparently enzymically catalyzed.</dcterms:abstract> <dc:creator>Stromeyer, Susanna A.</dc:creator> <dc:format>application/pdf</dc:format> <dc:contributor>Cook, Alasdair M.</dc:contributor> <dc:creator>Leisinger, Thomas</dc:creator> <dcterms:title>Biotransformation of Chloromethane to Methanethiol</dcterms:title> <dc:rights>deposit-license</dc:rights> <dcterms:bibliographicCitation>First publ. in: Environmental Science and Technology ; 27 (1993), 8. - S. 1577-1579</dcterms:bibliographicCitation> <dcterms:issued>1993</dcterms:issued> <dc:date rdf:datatype="">2011-03-24T17:32:41Z</dc:date> </rdf:Description> </rdf:RDF>

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