Localized Co2+ Doping of CdSe/CdS Seeded Nanorods

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FISCHLI, Danja, Luisa RIEGER, Klaus BOLDT, 2022. Localized Co2+ Doping of CdSe/CdS Seeded Nanorods. In: Journal of Physical Chemistry C: Nanomaterials and Interfaces. American Chemical Society (ACS). 126(29), pp. 12150-12158. ISSN 1932-7447. eISSN 1932-7455. Available under: doi: 10.1021/acs.jpcc.2c02081

@article{Fischli2022-07-28Local-58177, title={Localized Co2+ Doping of CdSe/CdS Seeded Nanorods}, year={2022}, doi={10.1021/acs.jpcc.2c02081}, number={29}, volume={126}, issn={1932-7447}, journal={Journal of Physical Chemistry C: Nanomaterials and Interfaces}, pages={12150--12158}, author={Fischli, Danja and Rieger, Luisa and Boldt, Klaus} }

eng Transition-metal-doped semiconductor nanocrystals have garnered interest in the field of spintronics because of their capability to couple an applied magnetic field to a photonic response, and vice versa. These structures are a synthetic challenge due to difficulties in controlling the distribution of dopants as well as introducing the impurity atoms into the host material in the first place. In this paper we present a route toward anisotropically Co<sup>2+</sup>-doped CdSe/CdS dot-in-rods, in which the dopants are localized at the nanorod tips, at a defined distance from the CdSe seed particle. The localized doping of seeded nanorods allows to gain a deeper understanding of the interaction of the dopant with an exciton through competitive photoluminescence quenching, highlighting the fact that the dopant locale is more important than dopant concentration. It also yields information about the kinetics that govern impurity diffusion, with an activation energy for Co<sup>2+</sup> in nanocrystalline CdS of E<sub>a</sub> = 61.11 kJ mol<sup>–1</sup>. 2022-07-28 Attribution-NonCommercial-NoDerivatives 4.0 International Boldt, Klaus Fischli, Danja Rieger, Luisa Fischli, Danja 2022-07-27T12:37:06Z Rieger, Luisa 2022-07-27T12:37:06Z Boldt, Klaus Localized Co<sup>2+</sup> Doping of CdSe/CdS Seeded Nanorods

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