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Tetraruthenium Macrocycles with Laterally Extended Bis(alkenyl)quinoxaline Ligands and Their F<sub>4</sub>TCNQ<sup>•−</sup> Salts

Tetraruthenium Macrocycles with Laterally Extended Bis(alkenyl)quinoxaline Ligands and Their F4TCNQ•− Salts

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DAS, Rajorshi, Michael LINSEIS, Laura SENFT, Ivana IVANOVIĆ-BURMAZOVIĆ, Rainer F. WINTER, 2022. Tetraruthenium Macrocycles with Laterally Extended Bis(alkenyl)quinoxaline Ligands and Their F4TCNQ•− Salts. In: Inorganics. MDPI. 10(6), 82. eISSN 2304-6740. Available under: doi: 10.3390/inorganics10060082

@article{Das2022-06-14Tetra-57953, title={Tetraruthenium Macrocycles with Laterally Extended Bis(alkenyl)quinoxaline Ligands and Their F4TCNQ•− Salts}, year={2022}, doi={10.3390/inorganics10060082}, number={6}, volume={10}, journal={Inorganics}, author={Das, Rajorshi and Linseis, Michael and Senft, Laura and Ivanović-Burmazović, Ivana and Winter, Rainer F.}, note={Article Number: 82} }

Senft, Laura Linseis, Michael Ivanović-Burmazović, Ivana Das, Rajorshi 2022-06-14 Das, Rajorshi Winter, Rainer F. 2022-07-06T12:16:38Z Attribution 4.0 International Linseis, Michael Winter, Rainer F. 2022-07-06T12:16:38Z Ivanović-Burmazović, Ivana Senft, Laura We report on the tetraruthenium macrocycles Ru<sub>4</sub>-5 and -6 with a π-conjugated pyrene-appended 5,8-divinylquinoxaline ligand and either isophthalate or thiophenyl-2,5-dicarboxylate linkers and their charge-transfer salts formed by oxidation with two equivalents of F<sub>4</sub>TCNQ. Both macrocyclic complexes were characterized by NMR spectroscopy, mass spectrometry, cyclic and square-wave voltammetry, and by IR, UV–vis–NIR, and EPR spectroscopy in their various oxidation states. eng Tetraruthenium Macrocycles with Laterally Extended Bis(alkenyl)quinoxaline Ligands and Their F<sub>4</sub>TCNQ<sup>•−</sup> Salts

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